Trichloro(4-chlorophenyl)stannane

Base Information

• Chemical Name: Trichloro(4-chlorophenyl)stannane
• CAS No.: 87669-43-0
• Molecular Formula: C₆H₄Cl₄Sn
• Molecular Weight: 336.62
• DSSTox Substance ID: DTXSID40517940
• Mol file: 87669-43-0.mol

Synonyms:Trichloro(4-chlorophenyl)stannane;87669-43-0;SCHEMBL11316802;DTXSID40517940

Chemical Property of Trichloro(4-chlorophenyl)stannane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 337.805963
• Heavy Atom Count: 11
• Complexity: 125

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC(=CC=C1Cl)[Sn](Cl)(Cl)Cl

Technology Process of Trichloro(4-chlorophenyl)stannane

There total 1 articles about Trichloro(4-chlorophenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.5%

4-chlorophenyl-methyl-dichlorosilane (825-93-4) + tin(IV) chloride (7646-78-8) → trichloro(p-chlorophenyl)stannane (87669-43-0)

Guidance literature:

With AlCl₃; In neat (no solvent); byproducts: CH3SiCl3; heated for 1 h to 125°C; stirred for 2 h; heated to 135-140°C and then at 145-150°C for 2 h; AlCl3 sepd.; vacuum-distd.; elem. anal.;

Reference yield: 84.0%

8-quinolinol (148-24-3,24804-14-6) + trichloro(p-chlorophenyl)stannane (87669-43-0) → p-chlorophenyl-tris(8-quinolinato)tin(IV) (245068-31-9)

Guidance literature:

With NH₃; In methanol; byproducts: NH4Cl; N2-atmosphere; addn. of Sn-compd. to mixt. of 4 equiv. ligand with concd. NH3, refluxing for 3 h; collection (filtration), washing (MeOH), drying (vac., over P2O5); elem. anal.;

DOI:10.1016/S0022-328X(99)00103-5

Reference yield: 70.0%

trichloro(p-chlorophenyl)stannane (87669-43-0) + sodium picolinate (57665-05-1) → (p-chlorophenyl)Sn(pyridine-2-carboxylate)3 * 2 H2O

Guidance literature:

In methanol; chloroform; according to F. Huber et al., Appl. Organometal. Chem. 11 (1997) 869; carboxylate in MeOH, Sn-compd. in CHCl3; elem. anal.;

DOI:10.1016/S0022-328X(99)00103-5

upstream raw materials:

4-chlorophenyl-methyl-dichlorosilane

tin(IV) chloride

Downstream raw materials:

p-chlorophenyl-tris(8-quinolinato)tin(IV)