1,1,3,3,3-Pentafluoropropene

Base Information

• Chemical Name: 1,1,3,3,3-Pentafluoropropene
• CAS No.: 690-27-7
• Molecular Formula: C3H F5
• Molecular Weight: 132.033
• Hs Code.: 2903399090
• European Community (EC) Number: 211-717-5
• UNII: PA8D7ZJF5T
• DSSTox Substance ID: DTXSID8061000
• Nikkaji Number: J28.346K
• Mol file: 690-27-7.mol

Synonyms:1,1,3,3,3-Pentafluoropropene;690-27-7;1,1,3,3,3-pentafluoroprop-1-ene;1,1,3,3,3-Pentafluoropropene-1;Propene, 1,1,3,3,3-pentafluoro-;1-Propene, 1,1,3,3,3-pentafluoro-;1,1,3,3,3-Pentafluoro-1-propene;1-Propene,1,1,3,3,3-pentafluoro-;PA8D7ZJF5T;2-Hydropentafluoropropylene;EINECS 211-717-5;C3HF5;2H-perfluoropropene;UNII-PA8D7ZJF5T;CF3CH=CF2;Fc-1223zc;SCHEMBL51427;DTXSID8061000;AMY6778;MFCD00042591;AKOS006230221;FT-0605993

Chemical Property of 1,1,3,3,3-Pentafluoropropene

Chemical Property:

• Vapor Pressure: 5950mmHg at 25°C
• Melting Point: -153°C
• Boiling Point: -21°C
• PSA: 0.00000
• Density: 1.336g/cm³
• LogP: 2.32910
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 131.99984084
• Heavy Atom Count: 8
• Complexity: 94.7

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,1,3,3,3-Pentafluoropropene 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F
• Statements: 12
• Safety Statements: 9-16-23-33

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Halogenated Aliphatics, Unsaturated
• Canonical SMILES: C(=C(F)F)C(F)(F)F

Technology Process of 1,1,3,3,3-Pentafluoropropene

There total 42 articles about 1,1,3,3,3-Pentafluoropropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,1,3,3,3-hexachloropropane (3607-78-1) → 1-chloro-1,1,3,3,3-pentafluoropropane (460-92-4) + 2H-pentafluoropropene (690-27-7) + 1,1,1,3,3,3-hexafluoropropane (690-39-1) + perchloropropene (1888-71-7)

Guidance literature:

With hydrogen fluoride; chlorine; antimonypentachloride; at 80 - 95 ℃; under 8517.48 - 10069 Torr;

Reference yield:

2,2-dichloro-1,1,1,3,3,3-hexafluoro-propane (1652-80-8) + 2-Chloro-F-propane (76-18-6) → 1,1,1,2,3,3,3-Heptafluoropropane (431-89-0) + 2H-pentafluoropropene (690-27-7) + perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) + 2-chloropentafluoropropene (2804-50-4) + 1,1,1,3,3,3-hexafluoropropane (690-39-1) + 2-chloro-1,1,1,3,3,3-hexafluoropropane (431-87-8,134308-72-8)

Guidance literature:

With hydrogen; 10% Pd/C; 10% Pd/C; at 100 - 500 ℃; for 0.000833333 - 0.00983333h; under 735.572 - 6546.59 Torr; Combinatorial reaction / High throughput screening (HTS);

Reference yield:

1-chloro-1,1,3,3,3-pentafluoropropane (460-92-4) → 2H-pentafluoropropene (690-27-7) + 1,1,2-Trichloro-1,2,2-trifluoroethane (76-13-1) + 1,1,1,3,3,3-hexafluoropropane (690-39-1) + 2-chloro-1,1,1,3,3,3-hexafluoropropane (431-87-8,134308-72-8)

Guidance literature:

With hydrogen fluoride; 20% CrCl3 on carbon; at 53 - 400 ℃; for 4.5h; Product distribution / selectivity;

upstream raw materials:

1-chloro-1,1,3,3,3-pentafluoropropane

1,1,1,3,3-pentafluoro-3-iodo-propane

1-bromo-1,1,3,3,3-pentafluoro-propane

1,1,1,3,3-pentafluoro-2,3-dichloropropane

Downstream raw materials:

1,1,1,3,3-pentafluoro-3-iodo-2-trifluoromethyl-propane

trifluoromethan

Hexafluoroethane

2,3-Dibromo-1,1,1,3,3-pentafluoropropane

Refernces

• 1、 -. "Preparation method of 1,1,3,3,3-pentafluoropropylene". Paragraph 0040-0045. . Retrieved 2019/04/27.
• 2、 -. "PROCESS FOR THE PRODUCTION OF CHLORINATED AND/OR FLUORINATED PROPENES". Page/Page column 8. . Retrieved 2011/04/25.