1,1,1,3-Tetrachlorotetrafluoropropane

Base Information

• Chemical Name: 1,1,1,3-Tetrachlorotetrafluoropropane
• CAS No.: 2268-46-4
• Molecular Formula: C3Cl4 F4
• Molecular Weight: 253.839
• Hs Code.: 2903772023
• European Community (EC) Number: 218-868-6
• UNII: A2Q3C067ZT
• DSSTox Substance ID: DTXSID2062296
• Nikkaji Number: J85.960E
• Wikidata: Q27273539
• Mol file: 2268-46-4.mol

Synonyms:1,1,1,3-Tetrachlorotetrafluoropropane;2268-46-4;1,1,1,3-TETRACHLORO-2,2,3,3-TETRAFLUOROPROPANE;CFC-214cb;EINECS 218-868-6;UNII-A2Q3C067ZT;Propane, 1,1,1,3-tetrachloro-2,2,3,3-tetrafluoro-;A2Q3C067ZT;1,1,2,2-Tetrafluorotetrachloropropane;Freon-214;SCHEMBL63001;1,1,1,3-tetrachloro-2,2,3,3-tetrafluoro-propane;DTXSID2062296;CFC-214;MFCD00039325;AKOS015848705;FT-0605928;A816310;Q27273539;1,1,1,3-tetrakis(chloranyl)-2,2,3,3-tetrakis(fluoranyl)propane

Chemical Property of 1,1,1,3-Tetrachlorotetrafluoropropane

Chemical Property:

• Melting Point: -93°C
• Refractive Index: 1.397
• Boiling Point: 114°C
• Flash Point: 28.9°C
• PSA: 0.00000
• Density: 1.744g/cm³
• LogP: 3.82350
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 253.866073
• Heavy Atom Count: 11
• Complexity: 150

Purity/Quality:

98%Min ^*data from raw suppliers

1,1,1,3-Tetrachlorotetrafluoropropane 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(F)(F)Cl)(C(Cl)(Cl)Cl)(F)F

Technology Process of 1,1,1,3-Tetrachlorotetrafluoropropane

There total 15 articles about 1,1,1,3-Tetrachlorotetrafluoropropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

polytetrafluoroethylene (116-14-3,82785-14-6) + trichlorofluoromethane (75-69-4) → 1,3-dichlorohexafluoropropane (662-01-1) + freon-214 (2268-46-4) + 1,1-dichlorohexafluoropropane (2729-28-4) + 1,1,1-trichloro-2,2,3,3,3-pentafluoropropane (4259-43-2)

Guidance literature:

With aluminium trichloride; at 30 - 50 ℃; for 10h;

DOI:10.1016/S0022-1139(00)82839-0

Reference yield: 72.0%

3-chloro-1,1,2,2-tetrafluoropropane (679-85-6) → freon-214 (2268-46-4) + 1,3-dichloro-1,1,2,2,3-pentafluoropropane (422-00-4) + 3,3-dichloro-1,1,1,2,2-pentafluoropropane (4071-01-6) + 1,1,1-trichloro-2,2,3,3-tetrafluoropropane (422-51-5)

Guidance literature:

With chlorine; In tetrachloromethane; at 0 ℃; for 2h; Further byproducts given; Irradiation;

DOI:10.1016/S0022-1139(00)82839-0

Reference yield: 36.0%

trichlorofluoromethane (75-69-4) + Chlorotrifluoroethylene (79-38-9,9036-80-0) → 1,1,1,2-tetrachloro-2,3,3,3-tetrafluoropropane (3175-64-2) + freon-214 (2268-46-4) + 1,1,2,2-tetrachloro-1,3,3,3-tetrafluoropropane (2268-44-2) + 1,1,3,3-tetrachloro-1,2,2,3-tetrafluoropropane (2354-04-3)

Guidance literature:

With aluminium trichloride;

upstream raw materials:

tetrachloromethane

polytetrafluoroethylene

1-chloro-1,1,2,2-tetrafluoropropane

1,3-dichloro-1,1,2,2,3-pentafluoropropane

Downstream raw materials:

1-chloro-1,1,2,2-tetrafluoropropane

3-chloro-1,1,2,2-tetrafluoropropane

2,2,3,3-tetrafluoro-3-chloropropionyl chloride

2-chlorotetrafluoropropionyl chloride

Refernces

• 1、 Yang, Zhen-Yu. "Preparation of highly fluorinated cyclopropanes and ring-opening reactions with halogens". . p. 4410 - 4416. Retrieved 2003.
• 2、 -. "Method and device for preparing 2,3,3,3-tetrafluoropropene". Paragraph 0084-0087; 0094-0097. . Retrieved 2019/01/14.
• 3、 -. "PROCESSES FOR PRODUCING AND COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE AND/OR 1,2,3,3-TETRAFLUOROPROPENE". Page/Page column 17. . Retrieved 2008/12/05.