1-METHYL-1-PROPYLPIPERIDINIUM BROMIDE

Base Information

• Chemical Name: 1-METHYL-1-PROPYLPIPERIDINIUM BROMIDE
• CAS No.: 88840-42-0
• Molecular Formula: C9H20N.Br
• Molecular Weight: 222.168
• Mol file: 88840-42-0.mol

Synonyms:Piperidinium,1-methyl-1-propyl-,bromide;N-metnhyl-N-propylpiperidinium bromide;

Chemical Property of 1-METHYL-1-PROPYLPIPERIDINIUM BROMIDE

Chemical Property:

• Melting Point: 248 °C(dec.)
• PSA: 0.00000
• LogP: -1.01030
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: Soluble in water

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Methyl-1-propylpiperidin-1-iumBromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-METHYL-1-PROPYLPIPERIDINIUM BROMIDE

There total 2 articles about 1-METHYL-1-PROPYLPIPERIDINIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

N-methylcyclohexylamine (626-67-5) + propyl bromide (106-94-5) → N-metnhyl-N-propylpiperidinium bromide (88840-42-0)

Guidance literature:

In chloroform; at 60 ℃; for 6h;

DOI:10.1055/s-1983-30523

Reference yield:

1-isopropyl-1-methyl-piperidinium; iodide (84437-36-5) → N-metnhyl-N-propylpiperidinium bromide (88840-42-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 30 percent / sodium thiophenoxide / acetonitrile; butan-2-one / Heating

2: CHCl₃ / Heating

With sodium thiophenolate; In chloroform; acetonitrile; butanone;

Reference yield: 97.0%

N-metnhyl-N-propylpiperidinium bromide (88840-42-0) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → N-methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (608140-12-1)

Guidance literature:

In water; for 1h;

upstream raw materials:

N-methylcyclohexylamine

propyl bromide

1-isopropyl-1-methyl-piperidinium; iodide

Downstream raw materials:

N-methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide

Refernces

• 1、 -. "Piperidine type ionic liquid and preparation method and application thereof". Paragraph 0035; 0042; 0048; 0052; 0056; 0060; 0067; 0068. . Retrieved 2019/05/04.
• 2、 Shi, Ping-Ping,Ye, Qiong,Li, Qiang,Wang, Hui-Ting,Fu, Da-Wei,Zhang, Yi,Xiong, Ren-Gen. "Crystal structures, phase transitions, and switchable dielectric behaviors: Comparison of a series of N-heterocyclic ammonium perchlorates". . p. 8221 - 8231. Retrieved 2015/05/13.