trans-1,4-Diaminocyclohexane

Base Information

• Chemical Name: trans-1,4-Diaminocyclohexane
• CAS No.: 2615-25-0
• Molecular Formula: C6H14N2
• Molecular Weight: 114.191
• Hs Code.: 29213000
• Mol file: 2615-25-0.mol

Synonyms:trans-1,4-Bisaminocyclohexane;trans-1,4-Cyclohexanediamine;1,4-trans-Diaminocyclohexane;

Chemical Property of trans-1,4-Diaminocyclohexane

Chemical Property:

• Appearance/Colour: off-white to brown crystals or chunks
• Vapor Pressure: 18 mm Hg ( 87.2 °C)
• Melting Point: 67-72 °C
• Refractive Index: 1.483
• Boiling Point: 199.4 °C at 760 mmHg
• PKA: 10.78±0.70(Predicted)
• Flash Point: 80 °C
• PSA: 52.04000
• Density: 0.939 g/cm³
• LogP: 1.61560
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility.: soluble in Methanol

Purity/Quality:

99% ^*data from raw suppliers

trans-Cyclohexane-1,4-diamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 22-34-20/21/22
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: trans-1,4-diaminocyclohexane be used as organic intermediates and epoxy curing agents. trans-1,4-Diaminocyclohexane was used in preparation of fully aliphatic polyimides. It was employed as the structure-directing agent in the synthesis of novel two-dimensional layered zinc phosphate.

Technology Process of trans-1,4-Diaminocyclohexane

There total 15 articles about trans-1,4-Diaminocyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.5%

→ N-chloramide sodium salt + trans-1,4-cyclohexyldiamine (2615-25-0)

Guidance literature:

Reference yield: 91.0%

→ cyclohexane-1,4-dicarboxylic acid-bis-N-chloramide + trans-1,4-cyclohexyldiamine (2615-25-0)

Guidance literature:

Reference yield: 35.6%

1,4-Cyclohexanediol (556-48-9) → trans-1,4-cyclohexyldiamine (2615-25-0) + cis-1,4-cyclohexanediamine (15827-56-2)

Guidance literature:

With dodecacarbonyl-triangulo-triruthenium; 4,5-bis((diisopropylphosphanyl)methyl)acridine; ammonia; In tert-Amyl alcohol; at 170 ℃; for 21h; Temperature; Inert atmosphere; Schlenk technique; Autoclave;

DOI:10.1002/cctc.201300407

upstream raw materials:

1,4-phenylenediamine

trans-1,4-di(carboxamido)cyclohexane

trans-1.4-bis-methoxycarbonylamino-cyclohexane

methyl cyclohexane

Downstream raw materials:

1,1'-(trans-1,4-Cyclohexylene)bis<3-(2-fluoroethyl)urea>

trans-1,4-cyclohexane diisocyanate

N-(4-amino-cyclohexyl)-2,2,2-trifluoro-acetamide

Refernces

• 1、 -. "PRODUCTION METHOD OF TRANS-DIAMINOCYCLOHEXANE". Paragraph 0062; 0073. . Retrieved 2016/12/16.
• 2、 Pingen, Dennis,Diebolt, Olivier,Vogt, Dieter. "Direct amination of bio-alcohols using ammonia". . p. 2905 - 2912. Retrieved 2013/10/21.