1-Benzyl-2-methylhydrazine

Base Information

• Chemical Name: 1-Benzyl-2-methylhydrazine
• CAS No.: 10309-79-2
• Molecular Formula: C₈H₁₂N₂
• Molecular Weight: 136.197
• Hs Code.: 2928000090
• UNII: 82474LO402
• DSSTox Substance ID: DTXSID70145634
• Nikkaji Number: J2.272A
• Wikidata: Q27269299
• Mol file: 10309-79-2.mol

Synonyms:1-Benzyl-2-methylhydrazine;10309-79-2;1-METHYL-2-BENZYLHYDRAZINE;2-Benzyl-1-methylhydrazine;Methyl benzylhydrazine;Hydrazine, 1-benzyl-2-methyl-;1-Methyl-2-benzyl-hydrazine;Hydrazine, 1-methyl-2-(phenylmethyl)-;Hydrazine, 2-benzyl-1-methyl-;HSDB 5124;Hydrazine, 1-methyl-2-(3-tolyl)-;BRN 0742353;UNII-82474LO402;82474LO402;3-15-00-00699 (Beilstein Handbook Reference);1-Mthyl-2-benzylhydrazine;SCHEMBL3501486;DTXSID70145634;MFCD01722687;AKOS006276520;METHYL-2-BENZYL-HYDRAZINE, 1-;AS-31434;LS-76422;1-METHYL-2-BENZYLHYDRAZINE [HSDB];EN300-1702685;Q27269299

Chemical Property of 1-Benzyl-2-methylhydrazine

Chemical Property:

• Vapor Pressure: 0.187mmHg at 25°C
• Melting Point: 59-61oC
• Refractive Index: 1.5880 (estimate)
• Boiling Point: 211°Cat760mmHg
• Flash Point: 80.3°C
• PSA: 24.06000
• Density: 0.973g/cm³
• LogP: 1.69240
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 136.100048391
• Heavy Atom Count: 10
• Complexity: 77.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-BENZYL-2-METHYLHYDRAZINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Hydrazines
• Canonical SMILES: CNNCC1=CC=CC=C1

Technology Process of 1-Benzyl-2-methylhydrazine

There total 5 articles about 1-Benzyl-2-methylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C24H26N2O2(2+)*Br(1-)*I(1-) → 1-benzyl-2-methylhydrazine (10309-79-2)

Guidance literature:

With hydrogenchloride; In water; for 0.166667h; Heating;

DOI:10.1023/B:RUCB.0000035662.78900.7c

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) + benzylmagnesium chloride (6921-34-2) → 1-benzyl-2-methylhydrazine (10309-79-2)

Guidance literature:

With diethyl ether;

DOI:10.1021/jo01219a002

Reference yield:

1-benzylidene-2-methylhydrazine (13466-29-0) → 1-benzyl-2-methylhydrazine (10309-79-2)

Guidance literature:

With diborane;

DOI:10.1039/j39700002707

upstream raw materials:

diazomethane

phenylmagnesium bromide

benzylmagnesium chloride

1-benzylidene-2-methylhydrazine

Downstream raw materials:

N'-benzyl-N-methyl-N-nitroso-hydrazine

1-Benzyl-3-methyl-4-oxo-3,4-dihydrophthalazin

Refernces