((Dimethylamino)methylene)dimethylammonium methyl sulphate

Base Information

• Chemical Name: ((Dimethylamino)methylene)dimethylammonium methyl sulphate
• CAS No.: 2013-91-4
• Molecular Formula: C6H16N2O4S
• Molecular Weight: 212.27
• Hs Code.: 2923900090
• European Community (EC) Number: 217-939-9
• DSSTox Substance ID: DTXSID50173950
• Mol file: 2013-91-4.mol

Synonyms:2013-91-4;((Dimethylamino)methylene)dimethylammonium methyl sulphate;MethanaMiniuM, 1-(diMethylaMino)-N,N-diMethyl-, Methyl sulfate (1:1);EINECS 217-939-9;dimethylaminomethylidene(dimethyl)azanium;methyl sulfate;SCHEMBL1231917;DTXSID50173950;AOOJBRIQPYLGMR-UHFFFAOYSA-M;N,N,N',N'-tetramethylformamidinium methylsulfate

Chemical Property of ((Dimethylamino)methylene)dimethylammonium methyl sulphate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 81.06000
• Density: g/cm³
• LogP: 0.02220
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 212.08307817
• Heavy Atom Count: 13
• Complexity: 151

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)C=[N+](C)C.COS(=O)(=O)[O-]

Technology Process of ((Dimethylamino)methylene)dimethylammonium methyl sulphate

There total 2 articles about ((Dimethylamino)methylene)dimethylammonium methyl sulphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethyl amine (124-40-3) + N,N-dimethyl-formamide (68-12-2,33513-42-7) + dimethyl sulfate (77-78-1) → N,N,N',N'-tetramethylformamidinium methyl sulfate (2013-91-4)

Guidance literature:

N,N-dimethyl-formamide; dimethyl sulfate; at 60 ℃; for 4h;

dimethyl amine; In tetrahydrofuran; toluene; for 1h; Reflux;

Reference yield:

(methoxymethylidene)dimethylammonium methyl sulfate (21511-55-7,34643-89-5) + dimethyl amine (124-40-3) → N,N,N',N'-tetramethylformamidinium methyl sulfate (2013-91-4)

Guidance literature:

In benzene; for 1h; Heating;

DOI:10.1021/jo00219a025

Reference yield: 77.0%

N,N,N',N'-tetramethylformamidinium methyl sulfate (2013-91-4) + dimethyl amine (124-40-3) → tris(dimethylamino)methane (5762-56-1)

Guidance literature:

dimethyl amine; With Trimethyl borate; sodium hydride; In tetrahydrofuran; cooling;

N,N,N',N'-tetramethylformamidinium methyl sulfate; In tetrahydrofuran; cooling;

upstream raw materials:

(methoxymethylidene)dimethylammonium methyl sulfate

dimethyl amine

N,N-dimethyl-formamide

dimethyl sulfate

Downstream raw materials:

Bis(dimethylamino)acetonitrile

bis(dimethylamino)methoxymethane

Bis-(dimethylamino)-N-aethylanilino-methan

tris(dimethylamino)methane

Refernces

• 1、 Wasserman, Harry H.,Ives, Jeffrey L.. "Reaction of Singlet Oxygen with Enamino Carbonyl Systems. A General Method for the Synthesis of α-Keto Derivatives of Lactones, Esters, Amides, Lactams, and Ketones". . p. 3573 - 3580. Retrieved 2007/10/02.