5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

Base Information

• Chemical Name: 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
• CAS No.: 16591-56-3
• Molecular Formula: C44H28 Fe N4
• Molecular Weight: 668.58
• Mol file: 16591-56-3.mol

Synonyms:Iron,[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-, (SP-4-1)-;Iron, [5,10,15,20-tetraphenylporphinato(2-)]- (8CI); Iron, [a,b,g,d-tetraphenylporphinato(2-)]-(7CI); 21H,23H-Porphine, 5,10,15,20-tetraphenyl-, iron complex;(Tetraphenylporphine)iron; (meso-Tetraphenylporphinato)iron; (a,b,g,d-Tetraphenylporphyrinato)iron;Iron meso-tetraphenylporphyrin; Iron tetraphenylporphine; Irontetraphenylporphyrin; Iron(II) meso-tetraphenylporphyrin; Iron(II)meso-tetraphenylporphyrinate; Iron(II) tetraphenylporphin;Tetraphenylporphineiron(II); [5,10,15,20-Tetraphenylporphinato(2-)]iron; [a,b,g,d-Tetraphenylporphyrinato(2-)]iron;a,b,g,d-Tetraphenylporphinatoiron(II)

Chemical Property of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 34.58000
• Density: g/cm³
• LogP: 6.43530

Purity/Quality:

99% ^*data from raw suppliers

5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride ≥94% (HPLC) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

There total 57 articles about 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + iron (7439-89-6) → 5,10,15,20-tetraphenyl porphyrin iron (16591-56-3)

Guidance literature:

In toluene; byproducts: H2; cocondensation of iron and toluene vapor at liq. nitrogen temp.; heating to -94.6°C; dropwise addn. of porphine soln. under nitrogen to the slurry (molar ratio Fe:porphine 4:1); gradually warming to 0°C, 1h; filtration; evapn. of filtrate;

DOI:10.1021/ja00251a040

Reference yield: 99.0%

Fe(5,10,15,20-tetraphenylporphyrinate)(C=C(p-ClC6H4)2) → 5,10,15,20-tetraphenyl porphyrin iron (16591-56-3) + bis(4-chlorophenyl)acetylene (1820-42-4)

Guidance literature:

DOI:10.1021/ja954097e

Reference yield: 95.0%

meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) → 5,10,15,20-tetraphenyl porphyrin iron (16591-56-3)

Guidance literature:

With mercury activated zinc; In toluene; byproducts: ZnCl2, amalgum; (He); a mixture of Fe-complex and mercury activated zinc stirred in toluene; filtered; crystd. by addn. of heptane;

DOI:10.1021/ja00542a011

upstream raw materials:

μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron]

meso-tetraphenylporphyrin iron(III) chloride

{(tris(2-pyridylmethyl)amine)(acetonitrile)copper(I)} perchlorate

5,10,15,20-tetraphenyl-21H,23H-porphine

Downstream raw materials:

(nitrosyl)(meso-tetraphenylporphyrinato)iron(II)

(5,10,15,20-tetraphenylporphinato)iron(II)-(C(Cl)SeCH₂C₆H₅)*H₂O

selenocarbonyl(5,10,15,20-tetraphenylporphinato)iron(II)

Fe(tetraphenylporphyrin)(imidazole)2

Refernces

• 1、 Hendrickson, David N.,Kinnaird, Michael G.,Suslick, Kenneth S.. "". . p. 1243 - 1244. Retrieved 1987.
• 2、 Hu, Chuanjiang,Noll, Bruce C.,Schulz, Charles E.,Scheidt, W. Robert. "Electronic configuration of five-coordinate high-spin pyrazole-ligated iron(II) porphyrinates". . p. 10984 - 10991. Retrieved 2010.
• 3、 Reimer, Kenneth J.,Sibley, Craig A.,Sams, John R.. "". . p. 5147 - 5149. Retrieved 1983.
• 4、 Li, Jianfeng,Lord, Richard L.,Noll, Bruce C.,Baik, Mu-Hyun,Schulz, Charles E.,Scheidt, W. Robert. "Cyanide: A strong-field ligand for ferrohemes and hemoproteins?". . p. 10144 - 10146. Retrieved 2008.
• 5、 Shirakawa, Yoshinori,Yano, Yuuki,Niwa, Yuki,Inabe, Kanako,Umezawa, Naoki,Kato, Nobuki,Hisamatsu, Yosuke,Higuchi, Tsunehiko. "Stable Iron Porphyrin Intramolecularly Coordinated by Alcoholate Anion: Synthesis and Evaluation of Axial Ligand Effect of Alcoholate on Spectroscopy and Catalytic Activity". . p. 4268 - 4274. Retrieved 2019.
• 6、 Kurtikyan, T. S.,Martirosyan, G. G.,Gasparyan, A. V.,Akopyan, M. E.,Zhamkochyan, G. A.. "". . . Retrieved 1990.
• 7、 Sheng, Tai-Cheng,Rebenstorf, Bernd,Wideloev, Anders,Larsson, Ragnar. "Pyrolysis of Metalloporphyrins Part 1. - Fourier-transform Infrared Study of Fe-Tetraphenylporphyrin Chloride". . p. 477 - 482. Retrieved 1992.
• 8、 Hieringer, Wolfgang,Flechtner, Ken,Kretschmann, Andreas,Seufert, Knud,Auwaerter, Willi,Barth, Johannes V.,Goerling, Andreas,Steinrueck, Hans-Peter,Gottfried, J. Michael. "The surface trans effect: Influence of axial ligands on the surface chemical bonds of adsorbed metalloporphyrins". . p. 6206 - 6222. Retrieved 2011.
• 9、 Nanthakumar, Alaganandan,Fox, Stephen,Karlin, Kenneth D.. "Copper-Dioxygen Reactivity Involved in the Formation of μ-oxoIII-O-CuIIL>+ Heterodinuclear Complexes (por = porphyrinate, L = tetradentate ligand), and Novel Synthesis of Square-Planar FeII(por) Species". . p. 499 - 501. Retrieved 1995.
• 10、 Grodkowski,Behar,Neta,Hambright. "Iron porphyrin-catalyzed reduction of CO2. Photochemical and radiation chemical studies". . p. 248 - 254. Retrieved 1997.