N1,N1-DIMETHYL-4-(DI[4-(DIMETHYLAMINO)PHENYL]PHOSPHORYL)ANILINE

Base Information

• Chemical Name: N1,N1-DIMETHYL-4-(DI[4-(DIMETHYLAMINO)PHENYL]PHOSPHORYL)ANILINE
• CAS No.: 807-20-5
• Molecular Formula: C24H30 N3 O P
• Molecular Weight: 407.495
• Mol file: 807-20-5.mol

Synonyms:Phosphineoxide, tris[p-(dimethylamino)phenyl]- (7CI,8CI);Tris-p-dimethylaminophenylphosphine oxide; Tris[4-(dimethylamino)phenyl]phosphineoxide

Chemical Property of N1,N1-DIMETHYL-4-(DI[4-(DIMETHYLAMINO)PHENYL]PHOSPHORYL)ANILINE

Chemical Property:

• Melting Point: 275 °C
• Boiling Point: 600.6oC at 760 mmHg
• Flash Point: 317.1oC
• PSA: 36.60000
• Density: 1.16g/cm3
• LogP: 3.52400

Purity/Quality:

99% ^*data from raw suppliers

N-(4-{BIS[4-(DIMETHYLAMINO)PHENYL]PHOSPHORYL}PHENYL)-N,N-DIMETHYLAMINE AldrichCPR ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of N1,N1-DIMETHYL-4-(DI[4-(DIMETHYLAMINO)PHENYL]PHOSPHORYL)ANILINE

There total 11 articles about N1,N1-DIMETHYL-4-(DI[4-(DIMETHYLAMINO)PHENYL]PHOSPHORYL)ANILINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

tris(p-N,N-dimethylaminophenyl)iodophosphonium iodide (37971-43-0) → tris(p-dimethylaminophenyl)phosphine oxide (807-20-5)

Guidance literature:

Reference yield: 55.0%

tris(p-dimethylaminophenyl)phosphine (1104-21-8) → tris(p-dimethylaminophenyl)phosphine oxide (807-20-5)

Guidance literature:

With sulfuric acid; dihydrogen peroxide; In ethanol; for 0.166667h; Inert atmosphere;

DOI:10.1002/chem.201502166

Reference yield:

C30H42N3O2P (73116-89-9) → 2,3-dimethyl-2,3-epoxybutane (5076-20-0) + tris(p-dimethylaminophenyl)phosphine oxide (807-20-5)

Guidance literature:

In benzene-d6; at 38 ℃; Rate constant;

DOI:10.1021/jo01306a010

upstream raw materials:

bis-(4-dimethylamino-phenyl)-hydroxyphosphine

N,N-dimethyl-aniline

4-dimethylaminophenyllithium

tris(p-N,N-dimethylaminophenyl)iodophosphonium iodide

Refernces

• 1、 -. "Preparation of organohalosilanes". . . Retrieved 2008/06/13.
• 2、 Feshchenko, N. G.,Rutkovskii, E. K.,Gorbatenko, Zh. K.. "REACTION OF PHOSPHORUS AND IODINE". . p. 1498 - 1499. Retrieved 2007/10/02.