Stannane, (4-methoxyphenyl)trimethyl-

Base Information

• Chemical Name: Stannane, (4-methoxyphenyl)trimethyl-
• CAS No.: 940-00-1
• Molecular Formula: C10H16OSn
• Molecular Weight: 270.946
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID10347377
• Wikidata: Q82121220
• Mol file: 940-00-1.mol

Synonyms:Stannane, (4-methoxyphenyl)trimethyl-;940-00-1;Stannane, (p-methoxyphenyl)trimethyl-;4-Methoxyphenyltrimethylstannane;(4-methoxyphenyl)trimethylstannane;SCHEMBL2480783;DTXSID10347377;(p-Methoxyphenyl)trimethylstannane;Trimethyl(p-methoxyphenyl)stannane;(4-Methoxyphenyl)(trimethyl)stannane #

Chemical Property of Stannane, (4-methoxyphenyl)trimethyl-

Chemical Property:

• PSA: 9.23000
• LogP: 1.88060
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 272.022318
• Heavy Atom Count: 12
• Complexity: 131

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)[Sn](C)(C)C

Technology Process of Stannane, (4-methoxyphenyl)trimethyl-

There total 22 articles about Stannane, (4-methoxyphenyl)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trimethyltin(IV)chloride (1066-45-1) + sodium (7440-23-5) + 4-methoxy-N,N,N-trimethylbenzenaminium iodide (17310-99-5) → (4-methoxyphenyl)trimethylstannane (940-00-1)

Guidance literature:

With methyl iodide; In ammonia; Irradiation (UV/VIS); condensation of sodium-dried ammonia into round-bottomed Pyrex flask, addn. of Me3SnCl and Na, addn. of CH3OC6H4NMe3I; irradn. with stirring for30 min, quenching by addn. of MeI in excess; evapn. of ammonia, treatment with water, extn. with ether;

DOI:10.1021/om000859p

Reference yield: 96.0%

para-iodoanisole (696-62-8) + hexamethyldistannane (661-69-8) → (4-methoxyphenyl)trimethylstannane (940-00-1)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; byproducts: Me3SnI; at 115°C for 15 h in sealed thick wall Pyrex glass ampoules;

DOI:10.1016/S0022-328X(00)84615-X

Reference yield: 94.0%

1-bromo-4-methoxy-benzene (104-92-7) + trimethyltin(IV)chloride (1066-45-1) → (4-methoxyphenyl)trimethylstannane (940-00-1)

Guidance literature:

With magnesium; methyl iodide; In tetrahydrofuran; THF soln. of ArBr was added dropwise to Mg metal, reaction was initiated with MeI, stirred for 2 h at 25°C under Ar, a soln. of Me3GeCl in THF was added dropwise, mixt. was refluxed for 2 h; cooled, treated with 5% aq. NH4Cl, extd. with CH2Cl2, ext. was washed with water, dried (Na2SO4), fractionated; elem. anal.;

DOI:10.1016/0022-328X(87)80344-3

upstream raw materials:

para-iodoanisole

hexamethyldistannane

diethyl 4-methoxyphenyl phosphate

trimethylstannyl sodium

Downstream raw materials:

4-methoxy-4'-nitrobenzophenone

4-methoxy-4'-nitrobiphenyl

5-(4-methoxyphenyl)tropolone

1-methoxy-4-(3-methyl-but-2-enyl)benzene

Refernces

• 1、 Kim, Hyunwoo,Kim, Hyungjun,Lambert, Tristan H.,Lin, Song. "Reductive Electrophotocatalysis: Merging Electricity and Light to Achieve Extreme Reduction Potentials". supporting information. p. 2087 - 2092. Retrieved 2020/02/04.
• 2、 Lian, Chang,Yue, Guanglu,Mao, Jinshan,Liu, Danyang,Ding, Yi,Liu, Zerong,Qiu, Di,Zhao, Xia,Lu, Kui,Fagnoni, Maurizio,Protti, Stefano. "Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones". . p. 5187 - 5191. Retrieved 2019/07/03.