Cyclododecane

Base Information

• Chemical Name: Cyclododecane
• CAS No.: 294-62-2
• Deprecated CAS: 46133-53-3
• Molecular Formula: C12H24
• Molecular Weight: 168.323
• Hs Code.: 29021990
• European Community (EC) Number: 206-033-9
• UNII: 97CN13ZD83
• DSSTox Substance ID: DTXSID9021552
• Nikkaji Number: J43.296B
• Wikipedia: Cyclododecane
• Wikidata: Q118040
• RXCUI: 2557361
• Metabolomics Workbench ID: 130646
• ChEMBL ID: CHEMBL3185808
• Mol file: 294-62-2.mol

Synonyms:BRN 1901008;

Chemical Property of Cyclododecane

Chemical Property:

• Appearance/Colour: white solid
• Vapor Pressure: 0.0413mmHg at 25°C
• Melting Point: 59-61 °C
• Refractive Index: 1.433
• Boiling Point: 246.999 °C at 760 mmHg
• Flash Point: 87.585 °C
• PSA: 0.00000
• Density: 0.791 g/cm³
• LogP: 4.68120
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: 16μg/L at 20℃
• XLogP3: 6.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 168.187800766
• Heavy Atom Count: 12
• Complexity: 43

Purity/Quality:

98% HPLC ^*data from raw suppliers

Cyclododecane >99.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
• Hazard Codes: R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
• Statements: R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Saturated (>C11)
• Canonical SMILES: C1CCCCCCCCCCC1
• Uses: Cyclododecane is considered as a new product in the conservation industry that is utilized as a temporary fixative, consolidant, barrier layer, and masking material in numerous fields of specialization. As a consolidant, it protects fragile ceramics while moving; therefore, allowing packaging and handling without any damage. As a temporary adhesive, cyclododecane has also been used remove subsequent of an adhesive without causing any damage. Its film-forming properties are one of the desirable working characteristics. The compound has been employed as a fixative for moisture-sensitive media on paper in the process of aqueous treatment. Due to its non-polar quality, cyclododecane can be used to protect materials that are solvent-sensitive during local solvent treatment. At room temperature, cyclododecane has the ability form a typically rigid solid, therefore, it has been used to secure friable substrates or flaking paint during transportation or during cleaning in surrounding. Moreover, it has been used to isolate the surface of an object when making mold. Cyclooctane and cyclononane are used as starting materials for organic synthesis. The major use of cyclododecane is as an intermediate for the production of chemicals used to make polyamides, polyesters, synthetic lubricating oils, and nylon 12; it is also used as a high-purity solvent. An emulsion of cyclododecane can be used to emulsify pesticides. It is also used as a mothproofing agent.

Technology Process of Cyclododecane

There total 96 articles about Cyclododecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

cyclododecene (1501-82-2) → cyclododecane (294-62-2)

Guidance literature:

With aluminum oxide; sodium tetrahydroborate; nickel dichloride; In hexane; at 40 ℃;

DOI:10.1016/S0040-4039(00)01084-4

Reference yield: 99.0%

(1E,5E,9Z)-cyclododeca-1,5,9-triene (706-31-0) → cyclododecane (294-62-2)

Guidance literature:

With hydrogen; at 240 ℃; under 760.051 Torr; Reagent/catalyst; Flow reactor;

DOI:10.1134/S1070363218010048

Reference yield: 99.0%

chlorocyclododecane (34039-83-3) → cyclododecane (294-62-2)

Guidance literature:

With triethylsilane; 2,6-bis(benzimidazole-2'-yl)pyridine; bis(1,5-cyclooctadiene)diiridium(I) dichloride; at 150 ℃; for 12h; Inert atmosphere;

DOI:10.1055/a-1527-4526

upstream raw materials:

Cyclodecene

cyclododecanone

buta-1,3-diene

methanol

Downstream raw materials:

cyclododecanol

cyclohexanone

cyclododecanone

Phosphoric acid cyclododecyl ester dimethyl ester

Refernces

• 1、 Qiao, Kun,Deng, Youquan. "A novel reaction in ionic liquids: Selective cyclization of 1-dodecene to cyclododecane under moderate pressure". . p. 2191 - 2193. Retrieved 2003.
• 2、 Gimisis, T.,Ballestri, M.,Ferreri, C.,Chatgilialoglu, C.,Boukherroub, R.,Manuel, G.. "5,10-Dihydro-Silanthrene as a Reagent for the Barton-McCombie Reaction". . p. 3897 - 3900. Retrieved 1995.
• 3、 Ishida, Naoki,Kamae, Yoshiki,Ishizu, Keigo,Kamino, Yuka,Naruse, Hiroshi,Murakami, Masahiro. "Sustainable System for Hydrogenation Exploiting Energy Derived from Solar Light". supporting information. p. 2217 - 2220. Retrieved 2021/02/16.
• 4、 Nebykov,Popov, Yu. V.,Mokhov,Shcherbakova,Zotov, Yu. L.. "Hydrogenation of 1,5,9-Cyclododecatriene in a Three-Phase System in the Presence of Nickel Nanoparticles Supported on NаX Zeolite". . p. 110 - 115. Retrieved 2021/03/18.