cis-Cyclodecene

Base Information

• Chemical Name: cis-Cyclodecene
• CAS No.: 3618-12-0
• Molecular Formula: C10H18
• Molecular Weight: 138.253
• European Community (EC) Number: 213-301-9
• NSC Number: 155648,105776
• DSSTox Substance ID: DTXSID201015997
• Nikkaji Number: J80.028G,J79.824J
• Wikipedia: Cyclodecene
• Mol file: 3618-12-0.mol

Synonyms:Cyclodecene;cis-Cyclodecene;(Z)-Cyclodecene;935-31-9;Cyclodecene, (Z)-;EINECS 213-301-9;1-Cyclodecene;Cyclodecene, cis;(9Z)-cyclodecene;3618-12-0;(1Z)-Cyclodecene;UCIYGNATMHQYCT-UPHRSURJSA-N;DTXSID201015997;NSC105776;NSC155648;NSC 105776;NSC-105776;NSC-155648

Chemical Property of cis-Cyclodecene

Chemical Property:

• Melting Point: -9 °C
• Refractive Index: n20/D 1.485
• Boiling Point: 193.3 °C at 760 mmHg
• Flash Point: 59.1 °C
• PSA: 0.00000
• Density: 0.809 g/cm³
• LogP: 3.67700
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 138.140850574
• Heavy Atom Count: 10
• Complexity: 80.2

Purity/Quality:

98%Min ^*data from raw suppliers

Cyclododecene 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 38
• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCCCC=CCCC1
• Isomeric SMILES: C1CCCC/C=C\CCC1

Technology Process of cis-Cyclodecene

There total 5 articles about cis-Cyclodecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

cyclodecanol (1502-05-2) → Cyclodecene (3618-12-0)

Guidance literature:

With p-toluenesulfonyl chloride; In pyridine; for 24h;

Reference yield: 35.0%

3-vinylcyclononanone (625123-19-5) → Cyclodecene (3618-12-0) + (E)-undeca-8,10-dien-2-one + (E/Z)-cycloundec-4-enone

Guidance literature:

at 620 ℃; under 0.015001 - 0.030002 Torr;

DOI:10.1002/hlca.200490150

Reference yield:

diethyl ether (60-29-7,927820-24-4) + bromocyclodecane (2749-64-6) + iodine (7553-56-2,12190-71-5,8031-47-8) → cyclodecane (293-96-9) + Cyclodecene (3618-12-0) + cyclodecanecarboxylic acid (3203-36-9) + dicyclodecyl (120620-90-8)

Guidance literature:

anschliessend Behandeln mit festem Kohlendioxid;

DOI:10.1002/hlca.19510340144

upstream raw materials:

cyclodecanol

diethyl ether

bromocyclodecane

iodine

Downstream raw materials:

cyclodecene oxide

1,10-decanedioic acid

cis-1,2-diethylcyclohexane

cyclodecane

Refernces

• 1、 Gruver, Brian C.,Adams, Jeramie J.,Arulsamy, Navamoney,Roddick, Dean M.. "Acceptor pincer chemistry of osmium: Catalytic alkane dehydrogenation by (CF3PCP)Os(cod)(H)". . p. 6468 - 6475. Retrieved 2013/12/04.
• 2、 Rueedi, Georg,Hansen, Hans-Juergen. "Diradical-promoted two-carbon ring-expansion reactions by thermal isomerization: Synthesis of functionalized macrocyclic ketones". . p. 1628 - 1665. Retrieved 2007/10/03.