Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-

Base Information

• Chemical Name: Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-
• CAS No.: 59414-23-2
• Molecular Formula: C8H16O2Si
• Molecular Weight: 172.299
• Hs Code.: 29310099
• European Community (EC) Number: 261-753-0
• Mol file: 59414-23-2.mol

Synonyms:Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-;59414-23-2;4-methoxybuta-1,3-dien-2-yloxy(trimethyl)silane;1-Methoxy-3-(trimethylsiloxy)-1,3-butadiene;1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene;(3-methoxy-1-methylene-allyloxy)-trimethyl-silane;1-methoxy-3-trimethylsilyloxybutadiene;2-trimethylsilyloxy-4-methoxybutadiene;1-methoxy-3-trimethylsilyloxy butadiene;1-methoxy-3-trimethylsilyloxy-butadiene;4-methoxy-2-trimethylsilyloxybut-1,3-diene;FT-0608007;FT-0608008;(3-methoxy-1 methylene-allyloxy)trimethylsilane;1-methoxy-3-(trimethylsilyloxy)-1-3-butadiene;1 -methoxy-3-(trimethylsilyloxy)-1-3-butadiene

Chemical Property of Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-

Chemical Property:

• Appearance/Colour: CLEAR LIGHT YELLOW TO BROWN LIQUID
• Refractive Index: n20/D 1.454(lit.)
• Boiling Point: 181.7 °C at 760 mmHg
• Flash Point: 45 °C
• PSA: 18.46000
• Density: 0.872 g/cm³
• LogP: 2.51170
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 172.091956283
• Heavy Atom Count: 11
• Complexity: 156

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene >95.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R10:Flammable.
• Hazard Codes: R10:Flammable.
• Statements: 10
• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC=CC(=C)O[Si](C)(C)C

Technology Process of Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-

There total 3 articles about Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

chloro-trimethyl-silane (75-77-4) + 4-methoxy-3-buten-2-one (4652-27-1) → 1-methoxy-3-<(trimethylsilyl)oxy>01,3-butadiene (59414-23-2)

Guidance literature:

With triethylamine; lithium bromide; In tetrahydrofuran; 1) -15 deg C, 1 h; 2) 40 deg C, 24 h;

Reference yield: 89.0%

4-methoxy-3-buten-2-one (4652-27-1) + trimethylsilyl trifluoromethanesulfonate (27607-77-8) → 1-methoxy-3-<(trimethylsilyl)oxy>01,3-butadiene (59414-23-2)

Guidance literature:

With triethylamine; In diethyl ether; at 0 ℃; Inert atmosphere;

DOI:10.1021/jo502146z

Reference yield:

chloro-trimethyl-silane (75-77-4) + trans-4-methoxy-3-buten-2-one (51731-17-0) → 1-methoxy-3-<(trimethylsilyl)oxy>01,3-butadiene (59414-23-2)

Guidance literature:

With sodium bromide; Yield given. Multistep reaction; 1.) DMF, room temperature, 20 min, 2.) room temperature, 8-10 h;

upstream raw materials:

chloro-trimethyl-silane

4-methoxy-3-buten-2-one

trans-4-methoxy-3-buten-2-one

trimethylsilyl trifluoromethanesulfonate

Downstream raw materials:

C₂₁H₂₃NO₂S

C₁₇H₂₁NO₄S

C₂₁H₂₃NO₃S

C₁₇H₂₃NO₂S

Refernces

• 1、 Hansson, Lars,Carlson, Rolf. "Efficient Synthesis of Siloxy Dienes from α,β-Unsaturated Ketones". . p. 188 - 192. Retrieved 2007/10/02.