Nickel, bis(diethylcarbamodithioato-S,S')-

Base Information

• Chemical Name: Nickel, bis(diethylcarbamodithioato-S,S')-
• CAS No.: 14267-17-5
• Molecular Formula: C₁₀H₂₀N₂NiS₄
• Molecular Weight: 355.236
• Mol file: 14267-17-5.mol

Synonyms:Nickel, bis(diethylcarbamodithioato-S,S')-;bis(diethylcarbamothioylthio)nickel;MFCD00137706

Chemical Property of Nickel, bis(diethylcarbamodithioato-S,S')-

Chemical Property:

• Melting Point: 259 °C
• Boiling Point: 176.4°Cat760mmHg
• Flash Point: 60.5°C
• PSA: 121.26000
• Density: g/cm³
• LogP: 3.62120
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 353.986275
• Heavy Atom Count: 17
• Complexity: 185

Purity/Quality:

98%,99%, ^*data from raw suppliers

Nickel Diethyldithiocarbamate >97.0%(T) ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22
• Safety Statements: 36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)C(=S)[S-].CCN(CC)C(=S)[S-].[Ni+2]

Technology Process of Nickel, bis(diethylcarbamodithioato-S,S')-

There total 33 articles about Nickel, bis(diethylcarbamodithioato-S,S')- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

nickel(II) chloride hexahydrate + sodium N,N-diethyldithiocarbamate (148-18-5) → bis(N,N-diethyldithiocarbamato)nickel(II) (1079097-20-3,14267-17-5,52610-81-8)

Guidance literature:

In water;

DOI:10.1021/acs.inorgchem.9b02430

Reference yield: 58.0%

[Ni(3,7-bis(2-aminoethyl)-1,3,5,7-tetraazabicyclo[3.3.1]nonane)](ClO4)2 + sodium N,N-diethyldithiocarbamate (148-18-5) → bis(N,N-diethyldithiocarbamato)nickel(II) (1079097-20-3,14267-17-5,52610-81-8)

Guidance literature:

In ethanol; water; to an aq. soln. of Ni-complex an ethanolic soln. of Na-salt was added dropwise with continuous stirring; ppt. was filtered, washed several times with distilled water and dried in vac.; elem. anal.;

DOI:10.1016/j.poly.2010.09.023

Reference yield:

nickel(II) chloride hexahydrate + sodium N,N-diethyldithiocarbamate (148-18-5) → nickel(II) diethyldithiocarbamate (14267-17-5,1079097-20-3,52610-81-8)

Guidance literature:

In water; extn. with CHCl3, washing of exts. with water;

DOI:10.1246/bcsj.54.3374

upstream raw materials:

hydrogenchloride

Ni((CH₃CH₂)2NCS₂)(CH₃CNOCNOHCH₃)

sodium N,N-diethyldithiocarbamate

disulfiram

Downstream raw materials:

bis(N,N-diethyldithiocarbamato)mercury(II)

nickel(II)

(cyano)(diethyldithiocarbamato)(triphenylphosphine)nickel(II)

(diethyldithiocarbamato)(isothiocyanato)(triphenylphosphine)nickel(II)

Refernces

• 1、 Richburg, Chase S.,Farnum, Byron H.. "Influence of Pyridine on the Multielectron Redox Cycle of Nickel Diethyldithiocarbamate". . . Retrieved 2019/11/14.
• 2、 Husain, Ahmad,Nami, Shahab A.A.,Singh, Suneel P.,Oves,Siddiqi. "Anagostic interactions, revisiting the crystal structure of nickel dithiocarbamate complex and its antibacterial and antifungal studies". . p. 33 - 40. Retrieved 2011/02/27.