Mercury(II) diethyldithiocarbamate

Base Information

• Chemical Name: Mercury(II) diethyldithiocarbamate
• CAS No.: 14239-51-1
• Molecular Formula: C10H20 Hg N2 S4
• Molecular Weight: 497.136
• DSSTox Substance ID: DTXSID301099807
• Mol file: 14239-51-1.mol

Synonyms:Bis(diethyldithiocarbamato)mercury;Mercury(II) diethyldithiocarbamate;DTXSID301099807

Chemical Property of Mercury(II) diethyldithiocarbamate

Chemical Property:

• Melting Point: 128.5°C
• Boiling Point: 88.75°C
• PSA: 134.68000
• LogP: 3.08330
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 498.021577
• Heavy Atom Count: 17
• Complexity: 219

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)C(=S)S[Hg]SC(=S)N(CC)CC

Technology Process of Mercury(II) diethyldithiocarbamate

There total 19 articles about Mercury(II) diethyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(N,N-diethyldithiocarbamato)cobalt(III) (13963-60-5) + mercury → bis(N,N-diethyldithiocarbamato)mercury(II) (14239-51-1) + bis(diethyldithiocarbamate)cobalt(II) (15974-34-2)

Guidance literature:

In dichloromethane; Electrochem. Process; cyclic voltammetry on Hg electrode at 22°C in CH2Cl2 in the presence of 0.1 M Bu4NClO4; electrochemical and spectrophotometrical monitoring;

Reference yield:

tris(N,N-diethyldithiocarbamato)cobalt(III) (13963-60-5) + mercury → bis(N,N-diethyldithiocarbamato)mercury(II) (14239-51-1) + cobalt (7440-48-4)

Guidance literature:

In dichloromethane; Electrolysis; controlled-potential electrolysis at Hg electrode in CH2Cl2 at 22°C; electrochemical and spectrophotometrical monitoring; Hg complex identified by comparison with authentic sample;

Reference yield:

mercury ion (14302-87-5) + sodium N,N-diethyldithiocarbamate (148-18-5) → bis(N,N-diethyldithiocarbamato)mercury(II) (14239-51-1)

Guidance literature:

With acetic acid or sodium acetate or NH₃; In water; titration of acetic acid or sodium acetate or NH3 containing Hg(NO3)2 soln. with aq. (C2H5)2NCSSNa soln. or the other way round;;

DOI:10.1016/0003-2670(56)80156-6 DOI:10.1016/0003-2670(56)80174-8

upstream raw materials:

tris(N,N-diethyldithiocarbamato)cobalt(III)

carbon disulfide

diethylamine

bis(N,N-diethyldithiocarbamato)zinc(II)

Downstream raw materials:

Hg(S₂CN(CH₂CH₃)2)(P(C₆H₁₁)3)(ClO₄)

Refernces

• 1、 Bond,Hendrickson,Martin,Moir,Page. "Electrochemical reduction and oxidation of cobalt(III) dithiocarbamates". . p. 3440 - 3446. Retrieved 2008/10/08.