Cobalt tris(diethyldithiocarbamate)

Base Information

• Chemical Name: Cobalt tris(diethyldithiocarbamate)
• CAS No.: 13963-60-5
• Molecular Formula: C₁₅H₃₀CoN₃S₆
• Molecular Weight: 503.812
• DSSTox Substance ID: DTXSID501336700
• Wikipedia: Cobalt_tris(diethyldithiocarbamate)
• Mol file: 13963-60-5.mol

Synonyms:Cobalt tris(diethyldithiocarbamate);DTXSID501336700;13963-60-5

Chemical Property of Cobalt tris(diethyldithiocarbamate)

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 503.009594
• Heavy Atom Count: 25
• Complexity: 73

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCN(CC)C(=S)[S-].CCN(CC)C(=S)[S-].CCN(CC)C(=S)[S-].[Co+3]

Technology Process of Cobalt tris(diethyldithiocarbamate)

There total 1 articles about Cobalt tris(diethyldithiocarbamate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Co2((C2H5)2NCS2)5(1+)*BF4(1-)=(Co2((C2H5)2NCS2)5)BF4 + N,N'-dicyclohexyldithiooxamide (122-36-1) → tris(N,N-diethyldithiocarbamato)cobalt(III) (13963-60-5) + Co((C2H5)2NCS2)2((C6H11)NHCSCSNH(C6H11))(1+)*BF4(1-)=(Co((C2H5)2NCS2)2((C6H11)NHCSCSNH(C6H11)))BF4

Guidance literature:

In dichloromethane; equimolar amt. of reactants reacted in CH2Cl2 for 1 h under reflux; solvent evapd. to dryness, extd. with min. EtOH, pptd. by adding of petroleum ether, recrystd. from CH2Cl2-ligroine; elem. anal.;

DOI:10.1016/S0020-1693(00)89150-1

Reference yield: 90.0%

(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II) (19978-61-1) + tris(N,N-diethyldithiocarbamato)cobalt(III) (13963-60-5) → (N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]palladium(II) tetrachlorocobaltate(II) * 0.5 dichloromethane

Guidance literature:

In acetonitrile; byproducts: tetraethylthiuram disulfide; refluxing (10 h); filtering, evapn. (reduced pressure), CH2Cl2 addn., pptn. on Et2O addn.,filtering, washing (Et2O), drying (vac.); elem. anal.;

DOI:10.1016/S0277-5387(97)00386-0

Reference yield: 89.0%

tris(N,N-diethyldithiocarbamato)cobalt(III) (13963-60-5) + [1,2-bis(diphenylphosphino)ethane]palladium(II) bromide (15630-11-2) → (N,N-diethyldithiocarbamato)[1,2-bis(diphenylphosphino)ethane]palladium(II) tetrabromocobaltate(II)

Guidance literature:

In acetonitrile; refluxing (10 h); filtering, evapn. (reduced pressure), CH2Cl2 addn., pptn. on Et2O addn.,filtering, washing (Et2O), drying (vac.); elem. anal.;

DOI:10.1016/S0277-5387(97)00386-0

upstream raw materials:

N,N'-dicyclohexyldithiooxamide

Downstream raw materials:

bis(N,N-diethyldithiocarbamato)mercury(II)

cobalt

bis(diethyldithiocarbamate)cobalt(II)

diethyldithiocarbamate