1,2,3,4,5-PENTACHLORO-6-IODOBENZENE

Base Information

• Chemical Name: 1,2,3,4,5-PENTACHLORO-6-IODOBENZENE
• CAS No.: 16478-18-5
• Molecular Formula: C6Cl5 I
• Molecular Weight: 376.236
• Hs Code.: 2903999090
• Mol file: 16478-18-5.mol

Synonyms:Benzene,pentachloroiodo- (6CI,8CI,9CI); 2,3,4,5,6-Pentachloroiodobenzene;Iodopentachlorobenzene; Pentachloroiodobenzene

Chemical Property of 1,2,3,4,5-PENTACHLORO-6-IODOBENZENE

Chemical Property:

• Vapor Pressure: 5.85E-05mmHg at 25°C
• Melting Point: 215-217℃
• Boiling Point: 356.8°Cat760mmHg
• Flash Point: 169.6°C
• PSA: 0.00000
• Density: 2.196g/cm³
• LogP: 5.55820

Purity/Quality:

98%Min ^*data from raw suppliers

1,2,3,4,5-Pentachloro-6-iodobenzene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2,3,4,5-PENTACHLORO-6-IODOBENZENE

There total 11 articles about 1,2,3,4,5-PENTACHLORO-6-IODOBENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

pentachlorobenzene (608-93-5) → 2,3,4,5,6-pentachloroiodobenzene (16478-18-5)

Guidance literature:

With Iodine monochloride; lithium tert-butoxide; In N,N-dimethyl-formamide; at 120 ℃; for 3h; Inert atmosphere;

DOI:10.1021/ol802411f DOI:10.1021/jo9015369

Reference yield: 41.0%

hexachlorobenzene (118-74-1,67471-27-6) → 2,3,4,5,6-pentachloroiodobenzene (16478-18-5)

Guidance literature:

hexachlorobenzene; With n-butyllithium; In tetrahydrofuran; hexane; for 0.333333h;

With iodine; In tetrahydrofuran; hexane; at -78 - 20 ℃;

DOI:10.1007/s11172-005-0341-1

Reference yield:

iodobenzene (591-50-4) + chlorine (7782-50-5) → 1-Chloro-4-iodobenzene (637-87-6) + 2,3,4,5,6-pentachloroiodobenzene (16478-18-5)

Guidance literature:

Sonnenlicht;

upstream raw materials:

pentachlorobenzene

2,3,4,5,6-pentachloroaniline

pentachlorophenylhydrazine

iodobenzene

Downstream raw materials:

2,2',3,4,5,6-hexachlorobiphenyl

PCB 195

Decachlorobiphenyl

1,2,3,4,6,7,8,9-octachloro-thianthrene

Refernces

• 1、 Do, Hien-Quang,Daugulis, Olafs. "A simple base-mediated halogenation of acidic sp2 C-H bonds under noncryogenic conditions". supporting information; experimental part. p. 421 - 423. Retrieved 2009/07/04.
• 2、 Burukin,Vasil'ev,Struchkova,Kachala,Zlotin. "Reactions of polychlorophenyllithium compounds with electrophiles". . p. 964 - 969. Retrieved 2007/10/03.