Performic acid

Base Information

• Chemical Name: Performic acid
• CAS No.: 107-32-4
• Molecular Formula: CH2 O3
• Molecular Weight: 62.0251
• Hs Code.: 2918300090
• European Community (EC) Number: 600-819-9
• UNII: XEL6R975Q4
• DSSTox Substance ID: DTXSID40902397
• Nikkaji Number: J53.105G
• Wikipedia: Performic_acid
• Wikidata: Q3269240
• Mol file: 107-32-4.mol

Synonyms:performic acid;peroxyformic acid

Chemical Property of Performic acid

Chemical Property:

• Vapor Pressure: 5.09mmHg at 25°C
• Boiling Point: 127.5°Cat760mmHg
• Flash Point: 67.5°C
• PSA: 46.53000
• Density: 1.341g/cm³
• LogP: 0.26830
• Water Solubility.: miscible with H2O, alcohol, ether; soluble benzene, chloroform [HAW93]
• XLogP3: -0.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 62.000393922
• Heavy Atom Count: 4
• Complexity: 17.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

PERFORMIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Explodes when shocked or heated or in contact with reducing materials, metals, and metallic oxides. Strong irritant and oxidizing agent.
• Hazard Codes: Explodes when shocked or heated or in contact with reducing materials, metals, and metallic oxides. Strong irritant and oxidizing agent.

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)OO
• Uses: Peroxyformic acid is used as an epoxidizingagent and in organic synthesis involvingoxidation and hydroxylation reactions. Performic Acid is used for oxidation, epoxidation and hydroxylation reactions.

Technology Process of Performic acid

There total 9 articles about Performic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) → formic acid (64-18-6) + Peroxyformic acid (107-32-4) + formylperoxy radical (56240-83-6)

Guidance literature:

With oxygen; at -261.2 ℃; Product distribution; Thermodynamic data; Irradiation; further matrices (Ar/O2, Ar); photooxidation in solid matrix, ΔH0(rx);

DOI:10.1021/j100220a011

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) → formic acid (64-18-6) + Peroxyformic acid (107-32-4) + formylperoxy radical (56240-83-6) + 1, 3-dioxetane

Guidance literature:

With oxygen; at -261.2 ℃; for 3h; Product distribution; Mechanism; Irradiation; UV photooxidation; other time; other temp;

DOI:10.1021/j150667a005

Reference yield:

formic acid (64-18-6) + acetic acid (64-19-7,77671-22-8) → peracetic acid (79-21-0) + Peroxyformic acid (107-32-4)

Guidance literature:

With dihydrogen peroxide; sulfuric acid; In water; at 20 ℃; Product distribution / selectivity; 1-hydroxy ethylene-1,1-diphosphonic acid (HEDPA) stabilizer; dipicolinic acid stabilizer;

upstream raw materials:

formic acid

dihydrogen peroxide

sulfuric acid

water

Downstream raw materials:

2-phenyl-chroman-3,4-dione

threo-9,10-dihydroxyoctadecanoic acid

erythro-9,10-dihydroxystearic acid

1,2-decanediol

Refernces

• 1、 Grassi, Guido,Oldani, Markus,Bauder, Alfred. "33. Synthesis of Concentrated 18O-Labelled Hydrogen Peroxide and of 2H-, 13C- and 18O-Labelled Peroxyformic Acid". . p. 400 - 404. Retrieved 1983.
• 2、 Reinbold, Julia,Koehler, Peter,Rychlik, Michael. "Quantitation of glutathione and its oxidation products in erythrocytes by multiple-label stable-isotope dilution". . p. 41 - 48. Retrieved 2014.
• 3、 Tyblewski, M.,Dommen, J.,Ha, T.-K.,Bauder, A.. "Vibrational spectra and normal coordinate analysis of isotopically labelled peroxyformic acid.". . p. 397 - 408. Retrieved 1991.
• 4、 Oldani, M.,Ha, T.-K.,Bauder, A.. "Microwave Spectrum, Dipole Moment, and Substitution Structure of Peroxyformic Acid". . p. 360 - 365. Retrieved 1983.
• 5、 Rajesh, Mathur,Kapila, Shubhen,Nam, Paul,Forciniti, Daniel,Lorbert, Stephen,Schasteen, Charles. "Enzymatic synthesis and characterization of L-methionine and 2-hydroxy-4-(methylthio)butanoic acid (HMB) co-oligomers". . p. 2461 - 2467. Retrieved 2003.
• 6、 Sasatsuki, Hitoshi,Nakazaki, Atsuo,Uchida, Koji,Shibata, Takahiro. "Quantitative analysis of oxidized vitamin B1 metabolites generated by hypochlorous acid". . p. 197 - 206. Retrieved 2020.
• 7、 Williams, Brad J.,Russell, William K.,Russell, David H.. "High-throughput method for on-target performic acid oxidation of MALDI-deposited samples". . p. 157 - 166. Retrieved 2010.
• 8、 Coupé, Florentin,Petitjean, Laurène,Anastas, Paul T.,Caijo, Frédéric,Escande, Vincent,Darcel, Christophe. "Sustainable oxidative cleavage of catechols for the synthesis of muconic acid and muconolactones including lignin upgrading". supporting information. p. 6204 - 6211. Retrieved 2020/10/18.
• 9、 -. "POLYMERIZABLE COMPOUND AND OPTICALLY ANISOTROPIC BODY". Paragraph 0193; 0198. . Retrieved 2018/11/21.