Hexyl(trimethyl)silane

Base Information

• Chemical Name: Hexyl(trimethyl)silane
• CAS No.: 3429-62-7
• Molecular Formula: C9H22 Si
• Molecular Weight: 158.359
• NSC Number: 111641
• DSSTox Substance ID: DTXSID20296807
• Nikkaji Number: J488.824C
• Wikidata: Q82037586
• Mol file: 3429-62-7.mol

Synonyms:hexyl-trimethyl-silane;3429-62-7;Hexyl(trimethyl)silane;Silane, hexyltrimethyl-;NSC111641;Hexyl(trimethyl)silane #;DTXSID20296807;WUMVEFJJSIUCJJ-UHFFFAOYSA-N;NSC-111641

Chemical Property of Hexyl(trimethyl)silane

Chemical Property:

• Vapor Pressure: 2.57mmHg at 25°C
• Boiling Point: 164.5°Cat760mmHg
• Flash Point: 38.4°C
• Density: 0.744g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 158.149077236
• Heavy Atom Count: 10
• Complexity: 71.3

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC[Si](C)(C)C

Technology Process of Hexyl(trimethyl)silane

There total 17 articles about Hexyl(trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

hexyltrichlorosilane (928-65-4) → trimethylhexylsilane (3429-62-7)

Guidance literature:

With CH₃MgBr; In not given;

DOI:10.1021/ja01207a035

Reference yield: 35.0%

chloro-trimethyl-silane (75-77-4) + trihexylaluminium (1116-73-0) → trimethylhexylsilane (3429-62-7) + di-n-hexyldimethylsilane (3429-61-6)

Guidance literature:

With potassium chloride; at 150 ℃; for 6h;

DOI:10.1007/BF00950024

Reference yield:

1-hexene (592-41-6,25067-06-5) + trimethylsilan (993-07-7) → trimethylhexylsilane (3429-62-7)

Guidance literature:

platinum;

DOI:10.1039/DT9770001519

upstream raw materials:

hexyltrichlorosilane

methylmagnesium bromide

chloro-trimethyl-silane

1-bromo-hexane

Refernces

• 1、 Barthélemy, Antoine,Glootz, Kim,Hanske, Annaleah,Krossing, Ingo,Scherer, Harald. "Ga+-catalyzed hydrosilylation? about the surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+and silylium catalysis with perfluoroalkoxyaluminate anions". . p. 439 - 453. Retrieved 2022/01/22.
• 2、 Matsuda, Isamu,Kato, Tomohisa,Sato, Susumu,Izumi, Yusuke. "REGIOCONTROLLED SYNTHESIS OF ALLYLSILANES BY MEANS OF RHODIUM(I) OR IRIDIUM(I) CATALYZED ISOMERIZATION OF OLEFINS". . p. 5747 - 5750. Retrieved 2007/10/02.