cyclopentyl formate

Base Information

• Chemical Name: cyclopentyl formate
• CAS No.: 62781-99-1
• Molecular Formula: C6H10 O2
• Molecular Weight: 114.144
• Mol file: 62781-99-1.mol

Synonyms:Cyclopentanol, formate (9CI);Cyclopentyl formate;NSC 250976;

Chemical Property of cyclopentyl formate

Chemical Property:

• Vapor Pressure: 6.07mmHg at 25°C
• Refractive Index: 1.439
• Boiling Point: 140.7°C at 760 mmHg
• Flash Point: 38.8°C
• Density: 1g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cyclopentyl formate

There total 10 articles about cyclopentyl formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

formic acid (64-18-6) + cyclopentene (142-29-0) → cyclopentyl formate (62781-99-1)

Guidance literature:

With tetra[N,N,N′,N′′,N′′-pentamethyl-N,N′′-bis(3-sulfopropyl)diethylenetriaminium] tris[silicotungstic acid] salt; In neat (no solvent); at 95 ℃; for 4h; Reagent/catalyst; Autoclave;

DOI:10.1080/00397911.2019.1580743

Reference yield: 87.0%

→ cyclopentyl formate (62781-99-1)

Guidance literature:

With Cu/Al₂O₃; dihydrogen peroxide; In chloroform; at 80 ℃; for 24h;

Reference yield: 75.0%

Cyclopentanol (96-41-3) + formic acid ethyl ester (109-94-4) → cyclopentyl formate (62781-99-1)

Guidance literature:

With cerium(IV) trifluoromethanesulfonate; at 20 ℃; for 2h;

DOI:10.1246/bcsj.72.455

upstream raw materials:

formic acid

Cyclopentanol

4-methylphenyl sulfonic acid (2-cyclopropylethyl) ester

formic acid cyanomethyl ester

Downstream raw materials:

2-cyclopentylethynyl benzene

Cyclopentanol

Refernces

• 1、 Takakis, Ioannis M.,Rhodes, Yorke E.. "ACETOLYSIS AND FORMOLYSIS OF (R)- AND (S)-1-DEUTERIO-2-CYCLOPROPYLETHYL p-TOLUENESULFONATES". . p. 4959 - 4962. Retrieved 1983.
• 2、 Chen, Cheng,Wang, Minyan,Lu, Hongjian,Zhao, Binlin,Shi, Zhuangzhi. "Enabling the Use of Alkyl Thianthrenium Salts in Cross-Coupling Reactions by Copper Catalysis". supporting information. p. 21756 - 21760. Retrieved 2021/08/30.
• 3、 -. "Method for preparing formate-type compound". Paragraph 0039; 0047; 0048. . Retrieved 2018/07/30.