Tricyclo[4.3.1.13,8]undecane

Base Information

• Chemical Name: Tricyclo[4.3.1.13,8]undecane
• CAS No.: 281-46-9
• Molecular Formula: C11H18
• Molecular Weight: 150.264
• Hs Code.: 2902199090
• Mol file: 281-46-9.mol

Synonyms:Homoadamantane

Chemical Property of Tricyclo[4.3.1.13,8]undecane

Chemical Property:

• Melting Point: 259-260 °C
• Boiling Point: 210.3±7.0 °C(Predicted)
• PSA: 0.00000
• Density: 0.955±0.06 g/cm3(Predicted)
• LogP: 3.22270

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tricyclo[4.3.1.13,8]undecane

There total 5 articles about Tricyclo[4.3.1.13,8]undecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Tricyclo<4.3.1.13.8>undecan-3-peroxycarbonsaeure-tert-butylester (56263-64-0) → homoadamantane (281-46-9) + acetone (67-64-1) + tert-butyl alcohol (75-65-0)

Guidance literature:

In ethylbenzene; at 80 ℃; Rate constant;

Reference yield:

Tricyclo<4.3.1.13.8>undecan-1-peroxycarbonsaeure-tert-butylester (79634-92-7) → homoadamantane (281-46-9) + acetone (67-64-1) + tert-butyl alcohol (75-65-0)

Guidance literature:

In ethylbenzene; at 80 ℃; Rate constant;

Reference yield:

homoadamantanyl chloride (27011-47-8) → homoadamantane (281-46-9) + 3-Hydroxyhomoadamantan (14504-80-4) + 3-Homoadamantyllithium (86550-19-8) + [3,3']Bi[tricyclo[4.3.1.13,8]undecyl] (32621-99-1)

Guidance literature:

With Li (2percent Na); In pentane; at 35 ℃; Product distribution; other halide: bromide; other solvent: Et₂O; other temperatures: -45 degC and -65 degC; var. times of sampling;

DOI:10.1021/jo00166a008

upstream raw materials:

homoadamantanyl chloride

thiophenol

1-(chloromethyl)-2-bromoadamantane

Tricyclo<4.3.1.1^3.8>undecan-3-peroxycarbonsaeure-tert-butylester

Downstream raw materials:

Homoadamantan-1-ol

3-Hydroxyhomoadamantan

1-adamantanemethanol

3,6-homoadamantanediol

Refernces

• 1、 Molle, G.,Bauer, P.,Dubois, J. E.. "High-Yield Direct Synthesis of a New Class of Tertiary Organolithium Derivatives of Polycyclic Hydrocarbons". . p. 2975 - 2981. Retrieved 2007/10/02.