3-HOMOADAMANTANOL

Base Information

• Chemical Name: 3-HOMOADAMANTANOL
• CAS No.: 14504-80-4
• Molecular Formula: C11H18 O
• Molecular Weight: 166.263
• Hs Code.: 2906199090
• Mol file: 14504-80-4.mol

Synonyms:3-Homoadamantanol;3-Hydroxyhomoadamantane

Chemical Property of 3-HOMOADAMANTANOL

Chemical Property:

• Melting Point: 274.5-275.5℃ (ligroine )
• Boiling Point: 263.7±8.0℃ (760 Torr)
• Flash Point: 109.4±10.9℃
• PSA: 20.23000
• Density: 1.116±0.06 g/cm3 (20 ºC 760 Torr)
• LogP: 2.33760
• Storage Temp.: 2-8°C

Purity/Quality:

98%Min ^*data from raw suppliers

Tricyclo[4.3.1.13,8]undecan-3-ol 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-HOMOADAMANTANOL

There total 31 articles about 3-HOMOADAMANTANOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

adamantylmethylamine (17768-41-1) → 3-Hydroxyhomoadamantan (14504-80-4)

Guidance literature:

With acetic acid; sodium nitrite; In water; at 90 ℃; for 1.5h;

DOI:10.1021/ja00306a019

Reference yield: 49.0%

homoadamantane (281-46-9) → Homoadamantan-1-ol (31061-64-0) + 3-Hydroxyhomoadamantan (14504-80-4)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In 1,2-dichloro-ethane; at 65 ℃; for 24h;

DOI:10.1055/s-1983-30308

Reference yield: 4.0%

3-azidohomoadamantane (63534-35-0) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 1-adamantanemethanol (770-71-8) + 1-benzyl(adamantane) (7131-11-5) + 3-Hydroxyhomoadamantan (14504-80-4)

Guidance literature:

With aluminium trichloride; at 18 ℃; for 7.5h;

DOI:10.1021/jo00320a023

upstream raw materials:

3-bromohomoadamantane

homoadamantanyl chloride

adamantylmethylamine

1-<(p-tolylsulfonyl)methoxy>adamantane

Downstream raw materials:

1-(bromomethyl)adamantane

1-Amino-homoadamantan

1-hydroxy-3-hydroxymethyladamantane

Homoadamantane-1-carboxylic acid

Refernces

• 1、 Mlinaric-Majerski, Kata,Kaselj, Mira. "1,2-Methanoadamantane: A Molecule with a Twist Bent ? Bond". . p. 4362 - 4363. Retrieved 1994.
• 2、 Nordlander,J.E. et al.. "-". . p. 4475 - 4484. Retrieved 1966.
• 3、 Molle, Gerard,Bauer, Pierre. "The Barbier Synthesis: A One-Step Grignard Reaction?". . p. 3481 - 3487. Retrieved 1982.
• 4、 Klimochkin, Yu. N.,Yudashkin,Zhilkina,Ivleva,Moiseev,Oshis, Ya. F.. "One-pot synthesis of cage alcohols". . p. 971 - 976. Retrieved 2017/09/07.