tricyclo[4.3.1.1~3,8~]undecane-1-carboxylic acid

Base Information

• Chemical Name: tricyclo[4.3.1.1~3,8~]undecane-1-carboxylic acid
• CAS No.: 31061-65-1
• Molecular Formula: C12H18O2
• Molecular Weight: 194.27
• Hs Code.: 2916209090
• Mol file: 31061-65-1.mol

Synonyms:tricyclo[4.3.1.1~3,8~]undecane-1-carboxylic acid;1-Homoadamantanecarboxylic acid

Chemical Property of tricyclo[4.3.1.1~3,8~]undecane-1-carboxylic acid

Chemical Property:

• Vapor Pressure: 6.18E-05mmHg at 25°C
• Boiling Point: 321.4°C at 760 mmHg
• Flash Point: 150.7°C
• PSA: 37.30000
• Density: 1.183g/cm³
• LogP: 2.67750

Purity/Quality:

98%min ^*data from raw suppliers

Tricyclo[4.3.1.1~3,8~]undecane-1-carboxylicAcid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tricyclo[4.3.1.1~3,8~]undecane-1-carboxylic acid

There total 10 articles about tricyclo[4.3.1.1~3,8~]undecane-1-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

formic acid (64-18-6) + <α,α-D2>-1-Adamantanmethanol (39165-44-1) → Homoadamantane-1-carboxylic acid (31061-65-1)

Guidance literature:

In sulfuric acid; at 23 - 25 ℃; for 62h; Mechanism; complete equilibration;

Reference yield: 62.0%

formic acid (64-18-6) + <3,5,7-D3>-1-Adamantanmethanol (81788-98-9) → Homoadamantane-1-carboxylic acid (31061-65-1)

Guidance literature:

In sulfuric acid; Mechanism; 1) 15 deg C, 3 h, 2) 6 d; complete equilibration;

Reference yield: 60.0%

formic acid (64-18-6) + <α-13C,α,α-D2>-1-Adamantanmethanol (81788-97-8) → Homoadamantane-1-carboxylic acid (31061-65-1)

Guidance literature:

In sulfuric acid; at 23 ℃; for 60h; Mechanism; complete equilibration;

upstream raw materials:

formic acid

1-adamantanemethanol

<α,α-D2>-1-Adamantanmethanol

<α-13C>-1-Adamantanmethanol

Downstream raw materials:

1-Amino-homoadamantan

1-Homoadamantylmethylketoxim-pikrat

Phenyl-tricyclo[4.3.1.1^3,8]undec-1-yl-methanone

Homoadamantane-1-carboxylic acid chloride

Refernces