4-tert-butylbenzenesulfonic acid

Base Information

• Chemical Name: 4-tert-butylbenzenesulfonic acid
• CAS No.: 1133-17-1
• Molecular Formula: C10H14 O3 S
• Molecular Weight: 214.285
• Mol file: 1133-17-1.mol

Synonyms:Benzenesulfonicacid, p-tert-butyl- (7CI,8CI); 4-tert-Butylbenzenesulfonic acid; NSC 290811;p-tert-Butylbenzenesulfonic acid

Chemical Property of 4-tert-butylbenzenesulfonic acid

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: 1.197g/cm³

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-tert-butylbenzenesulfonic acid

There total 6 articles about 4-tert-butylbenzenesulfonic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-tert-butylbenzenesulfonyl chloride (15084-51-2) → 4-(tert-butyl)benzenesulfonic acid (1133-17-1)

Guidance literature:

With water; In 1,4-dioxane; for 6h; Reflux;

DOI:10.1021/acs.orglett.1c00994

Reference yield:

tert-butylbenzene (253185-03-4,253185-04-5) → 4-(tert-butyl)benzenesulfonic acid (1133-17-1)

Guidance literature:

With sulfuric acid;

Reference yield:

1,4-di-tert-butylbenzene (1012-72-2) → 4-(tert-butyl)benzenesulfonic acid (1133-17-1)

Guidance literature:

With sulfuric acid; benzene;

DOI:10.1021/ja01287a002

upstream raw materials:

tert-butylbenzene

1,4-di-tert-butylbenzene

4-tert-butylbenzenesulfonyl chloride

benzene

Downstream raw materials:

tert-butylbenzene-4-sulphonic acid sodium salt

4-tert-butylbenzenesulfonyl chloride

Refernces

• 1、 Bourbon, Paul,Appert, Emeline,Martin-Mingot, Agnès,Michelet, Bastien,Thibaudeau, Sébastien. "Complementary Site-Selective Sulfonylation of Aromatic Amines by Superacid Activation". supporting information. p. 4115 - 4120. Retrieved 2021/06/21.
• 2、 Rubleva,Krut'ko,Mitchenko. "Reactivity of sterically hindered aromatic sulfonic acid derivatives: VII.* hydrolysis of arenesulfonyl chlorides in aqueous acetonitrile". . p. 1006 - 1009. Retrieved 2007/10/03.