tert-butylbenzene

Base Information

• Chemical Name: tert-butylbenzene
• CAS No.: 253185-03-4
• Molecular Formula: C₁₀H₁₄
• Molecular Weight: 134.221
• Mol file: 253185-03-4.mol

Synonyms:

Chemical Property of tert-butylbenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butylbenzene

There total 482 articles about tert-butylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1-(tert-butyl)-4-{[4-(tert-butyl)benzyl]oxy}benzene (1415730-50-5) → tert-butylbenzene (253185-03-4,253185-04-5) + tert-butylcyclohexane (3178-22-1) + 4-tert-butyltoluene (98-51-1) + 1-(tert-butyl)-4-methylcyclohexane (75736-66-2)

Guidance literature:

With hydrogen; In water; at 270 ℃; for 3h; under 16501.7 Torr;

DOI:10.1039/c5gc00326a

Reference yield: 78.0%

1-tert-butyl-4-phenoxybenzene (5331-28-2) → tert-butylbenzene (253185-03-4,253185-04-5) + N-phenyl-2-cyclohexylamine (1821-36-9)

Guidance literature:

With sodium tetrahydroborate; 10 wt% Pd(OH)2 on carbon; ammonia; In water; m-xylene; at 150 ℃; for 24h; Inert atmosphere; Sealed tube;

DOI:10.1021/acscatal.8b02214

Reference yield: 51.0%

[Pd(CH2CMe2Ph)(κ3-N,N′,N′′-(N,N-bis(pyrid-2-ylmethyl)-N-(3-hydroxypropyl)amine))][HCO3] → tert-butylbenzene (253185-03-4,253185-04-5) + 2-methyl-1-phenyl-2-propene (3290-53-7) + 2-Methyl-1-phenyl-2-propanol (100-86-7) + 1-ethylstyrene (2039-93-2) + (E)-2-phenyl-2-butene (768-00-3) + 2-phenyl-2-butanol (1565-75-9,19641-57-7)

Guidance literature:

With dihydrogen peroxide; In water; water-d2; for 0.05h;

DOI:10.1021/acs.organomet.7b00631

upstream raw materials:

phosgene

diethyl ether

neophyl chloride

fluorobenzene

Downstream raw materials:

1-(tert-butyl)-4-(1-phenylethyl)benzene

4-(4-tert-butylphenyl)-4-oxobutyric acid

1-tert-butyl-4-(1,1,3,3-tetramethyl-butyl)-benzene

4,4'-di-tert-butylbenzophenone

Refernces

• 1、 Bartsch, Richard A.,Juri, Pedro N.. "Complexation of Arenediazonium Ions by Macrocyclic Multidentate Compounds". . p. 1011 - 1014. Retrieved 1980.
• 2、 Senkowski. "-". . p. 2974. Retrieved 1891.
• 3、 Roth, Ulrich,Mueller, Annerose,Kohlheim, Klaus,Mietchen, Ralf. "ULTRASOUND-FORCED ACTIVATION OF ALKANES IN ANHYDROUS HYDROFLUORIC ACID SYSTEMS". . p. 174. Retrieved 1985.
• 4、 Simons,Archer,Passino. "-". . p. 2956. Retrieved 1938.
• 5、 Huston,Barrett. "-". . p. 657,661. Retrieved 1946.
• 6、 Zhao, Dongpu,Wang, Yanan,Chu, Weifeng,Wang, Xinyi,Zhu, Xiangxue,Li, Xiujie,Xie, Sujuan,Wang, Hongxia,Liu, Shenglin,Xu, Longya. "Direct synthesis of hollow single-crystalline zeolite beta using a small organic lactam as a recyclable hollow-directing agent". . p. 10795 - 10804. Retrieved 2019.
• 7、 Nightingale,Taylor,Smelser. "-". . p. 258,260. Retrieved 1941.
• 8、 Wang, Hao-Ran,Wang, Xi–Chao,Xu, Xiufang,Zhao, Dongbing. "Ring Expansion to 8-Membered Silacycles through Formal Cross-Dimerization of 5-Membered Palladacycles with Silacyclobutanes". . p. 3039 - 3042. Retrieved 2021.
• 9、 Du, Linlin,Sun, Li,Zhang, Hua. "Photochemical and electrochemical C-N borylation of arylhydrazines". supporting information. p. 1716 - 1719. Retrieved 2022/02/21.
• 10、 Chernowsky, Colleen P.,Chmiel, Alyah F.,Wickens, Zachary K.,Williams, Oliver P.,Yeung, Charles S.. "Non-innocent Radical Ion Intermediates in Photoredox Catalysis: Parallel Reduction Modes Enable Coupling of Diverse Aryl Chlorides". supporting information. p. 10882 - 10889. Retrieved 2021/07/31.