1-tert-butyl-4-methylcyclohexane

Base Information

• Chemical Name: 1-tert-butyl-4-methylcyclohexane
• CAS No.: 75736-66-2
• Molecular Formula: C11H22
• Molecular Weight: 154.296
• Mol file: 75736-66-2.mol

Synonyms:Cyclohexane,1-tert-butyl-4-methyl- (7CI); 1-tert-Butyl-4-methylcyclohexane; NSC 29904

Chemical Property of 1-tert-butyl-4-methylcyclohexane

Chemical Property:

• Vapor Pressure: 1.01mmHg at 25°C
• Boiling Point: 184.2°Cat760mmHg
• Flash Point: 56.3°C
• Density: 0.8g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-tert-butyl-4-methylcyclohexane

There total 19 articles about 1-tert-butyl-4-methylcyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1-(tert-butyl)-4-{[4-(tert-butyl)benzyl]oxy}benzene (1415730-50-5) → tert-butylbenzene (253185-03-4,253185-04-5) + tert-butylcyclohexane (3178-22-1) + 4-tert-butyltoluene (98-51-1) + 1-(tert-butyl)-4-methylcyclohexane (75736-66-2)

Guidance literature:

With hydrogen; In water; at 270 ℃; for 3h; under 16501.7 Torr;

DOI:10.1039/c5gc00326a

Reference yield: 73.0%

4-tert-butyl-1-methylcyclohexyl bromide (910620-53-0) → 1-(tert-butyl)-4-methylcyclohexane (75736-66-2)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; for 2h; Heating;

DOI:10.1021/ja00037a007

Reference yield: 50.0%

(3r,6r)-6-(tert-butyl)-1-oxaspiro[2.5]octane (18881-26-0) → cis-(4-tert-butylcyclohexyl)methanol (13004-06-3,20691-53-6,10601-39-5) + 1-(tert-butyl)-4-methylcyclohexane (75736-66-2) + trans-(4-tert-butyl-cyclohexyl)-methanol (10601-39-5,20691-53-6,13004-06-3)

Guidance literature:

With hydrogen; nickel; In cyclohexane; at 20 ℃; under 760 Torr;

upstream raw materials:

methyl cyclohexane

isobutene

6-tert-Butyl-1-oxa-spiro[2.5]octane

(3r,6r)-6-(tert-butyl)-1-oxaspiro[2.5]octane

Downstream raw materials:

Menthane

Refernces

• 1、 Huang, Yao-Bing,Yan, Long,Chen, Meng-Yuan,Guo, Qing-Xiang,Fu, Yao. "Selective hydrogenolysis of phenols and phenyl ethers to arenes through direct C-O cleavage over ruthenium-tungsten bifunctional catalysts". . p. 3010 - 3017. Retrieved 2015/05/27.
• 2、 Accrombessi, Georges,Geneste, Patrick,Olive, Jean-Louis,Pavia, Andre Armand. "Hydrogenolyse en phase liquide des epoxydes du t-butyl-4 methylene-cyclohexane sur divers catalyseurs metalliques supportes". . p. 19 - 23. Retrieved 2007/10/02.