1-Iodododecane

Base Information

• Chemical Name: 1-Iodododecane
• CAS No.: 4292-19-7
• Molecular Formula: C12H25I
• Molecular Weight: 296.235
• Hs Code.: 29033990
• European Community (EC) Number: 224-293-1
• NSC Number: 9285
• DSSTox Substance ID: DTXSID1049302
• Nikkaji Number: J205.687I
• Wikidata: Q72483594
• ChEMBL ID: CHEMBL3181940
• Mol file: 4292-19-7.mol

Synonyms:1-iodododecane

Chemical Property of 1-Iodododecane

Chemical Property:

• Appearance/Colour: Clear colorless liquid
• Vapor Pressure: 0.00221mmHg at 25°C
• Melting Point: -3 °C(lit.)
• Refractive Index: n20/D 1.484(lit.)
• Boiling Point: 298.8 °C at 760 mmHg
• Flash Point: 113.5 °C
• PSA: 0.00000
• Density: 1.206 g/cm³
• LogP: 5.34230
• Storage Temp.: Store below +30°C.
• Sensitive.: Light Sensitive
• Water Solubility.: Insoluble
• XLogP3: 7.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 296.10010
• Heavy Atom Count: 13
• Complexity: 81.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Iodododecane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCCCCCCCI
• Uses: 1-Iodododecane has been used in the preparation of dodecylated graphite, alkyl functionalized single walled carbon nanotubes (SWNTs). It is also used as chemical intermediate.

Technology Process of 1-Iodododecane

There total 14 articles about 1-Iodododecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.9%

1-dodecyl alcohol (112-53-8) → 1-Iodododecane (4292-19-7)

Guidance literature:

With phosphorus; iodine; at 150 ℃; for 5h;

DOI:10.1142/S1088424611003616

Reference yield: 99.0%

dodecyl mesylate (51323-71-8) → 1-Iodododecane (4292-19-7)

Guidance literature:

With lithium iodide; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1002/adsc.201100736

Reference yield: 99.0%

1-dodecylbromide (143-15-7) → 1-Iodododecane (4292-19-7)

Guidance literature:

With sodium iodide; In acetone; at 20 ℃; for 55.5h; Inert atmosphere;

DOI:10.1002/anie.201711599

upstream raw materials:

1-dodecyl alcohol

1-dodecylbromide

1-dodecene

carbonochloridic acid 1-chloro-ethyl ester

Downstream raw materials:

1-dodecylpiperidine

1,4-didodecylpiperazine

tridodecylamine

heptadecan-4-one

Refernces

• 1、 Okamoto, Sentaro,Takano, Kouichi,Ishikawa, Tomohiro,Ishigami, Satoshi,Tsuhako, Akiko. "Activity and behavior of imidazolium salts as a phase transfer catalyst for a liquid-liquid phase system". . p. 8055 - 8058. Retrieved 2006.
• 2、 -. "NUCLEOSIDE PRODRUGS AND USES RELATED THERETO". Page/Page column 131; 132. . Retrieved 2021/02/26.
• 3、 Chen, Yifeng,Qu, Jingping,Wu, Xianqing. "Quinim: A New Ligand Scaffold Enables Nickel-Catalyzed Enantioselective Synthesis of α-Alkylated ?-Lactam". supporting information. p. 15654 - 15660. Retrieved 2020/10/18.