Dichloromethyl(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane

Base Information

• Chemical Name: Dichloromethyl(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane
• CAS No.: 73609-36-6
• Molecular Formula: C9H7Cl2F13Si
• Molecular Weight: 461.125
• Hs Code.: 2931900090
• European Community (EC) Number: 277-551-0
• DSSTox Substance ID: DTXSID00223797
• Nikkaji Number: J267.441F
• Wikidata: Q81985576
• Mol file: 73609-36-6.mol

Synonyms:73609-36-6;1h,1h,2h,2h-Perfluorooctylmethyldichlorosilane;Dichloromethyl(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane;dichloro-methyl-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane;EINECS 277-551-0;(1h,1h,2h,2h-perfluorooctyl)methyldichlorosilane;dichloro(methyl)(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane;Dichloromethyl((perfluorohexyl)ethyl)silane;EC 277-551-0;(tridecafluoro-1,1,2,2-tetrahydrooctyl)methyldichlorosilane;Silane, dichloromethyl(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-;C9H7Cl2F13Si;bis(chloranyl)-methyl-[3,3,4,4,5,5,6,6,7,7,8,8,8-tridecakis(fluoranyl)octyl]silane;SCHEMBL366529;C9-H7-Cl2-F13-Si;DTXSID00223797;1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluorooctylmethyldichlorosilane;MFCD00042360;AKOS025295667;CS-0455256;FT-0607825;1H,1H,2H,2H-Perfluoroctylmethyldichlorosilane;2-(Tridecafluorohexyl)ethyldichloro(methyl)silane;A837873;A838739;(Tridecafluoro-1,1,2,2-Tetrahydroctyl)Methyldichlorosilane;(Tridecafluoro-1,1,2,2-tetrahydrooctyl)-1-methyldichlorosilane;(Tridecafluoro-1,1,2,2-Tetrahydroctyl)Methylbis(Dimethylamino)Silane

Chemical Property of Dichloromethyl(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane

Chemical Property:

• Appearance/Colour: colorless liquid
• Vapor Pressure: 0.267mmHg at 25°C
• Refractive Index: 1.35
• Boiling Point: 211.3 °C at 760 mmHg
• Flash Point: 81.6 °C
• PSA: 0.00000
• Density: 1.503 g/cm³
• LogP: 6.66490
• Sensitive.: Moisture Sensitive
• Water Solubility.: 4.8μg/L at 20℃
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 13
• Rotatable Bond Count: 7
• Exact Mass: 459.9486483
• Heavy Atom Count: 25
• Complexity: 484

Purity/Quality:

99.9% ^*data from raw suppliers

1H,1H,2H,2H-Perfluorooctylmethyldichlorosilane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C,F
• Hazard Codes: C,F
• Statements: 10-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Chlorosilanes
• Canonical SMILES: C[Si](CCC(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(Cl)Cl

Technology Process of Dichloromethyl(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane

There total 1 articles about Dichloromethyl(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

Dichloromethylsilane (75-54-7) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene (25291-17-2) → (1H,1H,2H,2H-tridecafluoro-octyl)(methyl)dichlorosilane (73609-36-6)

Guidance literature:

With dihydrogen hexachloroplatinate; In isopropyl alcohol; at 100 ℃; for 18h;

DOI:10.1016/0022-1139(93)02999-U

Reference yield: 53.8%

sodium methylate (124-41-4) + (1H,1H,2H,2H-tridecafluoro-octyl)(methyl)dichlorosilane (73609-36-6) → 1H,1H,2H,2H-tridecafluorooctyl(dimethoxy)(methyl)silane (85857-17-6)

Guidance literature:

In methanol; 1,1,2-Trichloro-1,2,2-trifluoroethane; for 1h; Ambient temperature;

DOI:10.1246/bcsj.66.472

Reference yield:

3-(1,3-dioxolan-2-yl)-phenylbromide (17789-14-9) + (1H,1H,2H,2H-tridecafluoro-octyl)(methyl)dichlorosilane (73609-36-6) → C27H25F13O4Si

Guidance literature:

3-(1,3-dioxolan-2-yl)-phenylbromide; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 60 ℃; for 1.5h; Inert atmosphere;

(1H,1H,2H,2H-tridecafluoro-octyl)(methyl)dichlorosilane; In tetrahydrofuran; hexane; at 20 ℃; Inert atmosphere;

DOI:10.1002/ejoc.201300932

upstream raw materials:

Dichloromethylsilane

3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene

Downstream raw materials:

1H,1H,2H,2H-tridecafluorooctyl(dimethoxy)(methyl)silane

Refernces

• 1、 Yoshino, Norio,Yamamoto, Yasushi,Seto, Tsuyoshi,Tominaga, Shin-ichi,Kawase, Tokuzo. "Syntheses and Reaction of Metal Organics. XVII. Synthesis of Silane Coupling Agent Having Fluorocarbon Chain and Surface Modification of Glass Plate". . p. 472 - 476. Retrieved 2007/10/02.