Tris(acetonitrile)trichlororhodium

Base Information

• Chemical Name: Tris(acetonitrile)trichlororhodium
• CAS No.: 58166-91-9
• Molecular Formula: C₆H₉Cl₃N₃Rh
• Molecular Weight: 332.422
• DSSTox Substance ID: DTXSID30944327
• Mol file: 58166-91-9.mol

Synonyms:Tris(acetonitrile)trichlororhodium;(OC-6-22)-Tris(acetonitrile)trichlororhodium;Rhodium, tris(acetonitrile)trichloro-, (OC-6-22)-;21712-45-8;DTXSID30944327;Pyridin-4-ylmethanaminehydrochloride;fac-Tris(acetonitrile)trichlororhodium;58166-91-9;LS-143691;A8827;Rhodium(3+) chloride--acetonitrile (1/3/3)

Chemical Property of Tris(acetonitrile)trichlororhodium

Chemical Property:

• Vapor Pressure: 171mmHg at 25°C
• Boiling Point: 63.5°Cat760mmHg
• Flash Point: 5.6°C
• PSA: 36.09000
• Density: g/cm³
• LogP: 4.30074
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 330.89170
• Heavy Atom Count: 13
• Complexity: 29.3

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC#N.CC#N.CC#N.[Cl-].[Cl-].[Cl-].[Rh+3]

Technology Process of Tris(acetonitrile)trichlororhodium

There total 12 articles about Tris(acetonitrile)trichlororhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

rhodium(III) chloride trihydrate → fac-RhCl3(CH3CN)3 (15747-79-2,21712-45-8,58166-91-9)

Guidance literature:

In acetonitrile; boiling, pptd. addn. of ether;

DOI:10.1021/ic50075a014 DOI:10.1016/0020-1650(68)80026-1

Reference yield:

rhodium(III) chloride trihydrate + acetonitrile (75-05-8,26809-02-9) → mer-RhCl3(CH3CN)3 (15747-79-2,21712-45-8,58166-91-9)

Guidance literature:

In ethanol; acetonitrile; reflux in 1:1 ethanol/acetonitrile for 4h;

DOI:10.1021/ic50075a014

Reference yield:

fac-RhCl3(CH3CN)3 (15747-79-2,21712-45-8,58166-91-9) → mer-RhCl3(CH3CN)3 (15747-79-2,21712-45-8,58166-91-9)

Guidance literature:

In acetonitrile; heating;

DOI:10.1016/0020-1650(68)80026-1

upstream raw materials:

acetonitrile

rhodium(III)chloride

chloro-trimethyl-silane

dirhodium butyrate

Downstream raw materials:

fac-Rh(PF(OPh)2)3Cl₃

mer-{RhCl₃(C₆H₅CH₂CN)3}

mer-RhCl₃(CH₃CN)3

Refernces

• 1、 Yang, Zhiyong,Oki, Hiroki,Ebihara, Masahiro,Kawamura, Takashi. "Bis[dirhodium(II)] complexes with a Rh4(μ-Cl)4 core: Preparation and characterization". . p. 2277 - 2278. Retrieved 2007/10/03.