Methoxytriphenylsilane

Base Information

• Chemical Name: Methoxytriphenylsilane
• CAS No.: 1829-41-0
• Molecular Formula: C19H18 O Si
• Molecular Weight: 290.437
• Hs Code.: 2931900090
• European Community (EC) Number: 217-382-1
• DSSTox Substance ID: DTXSID30171358
• Nikkaji Number: J120.998A
• Wikidata: Q83041433
• Mol file: 1829-41-0.mol

Synonyms:Methoxytriphenylsilane;1829-41-0;Methoxy(triphenyl)silane;Benzene, 1,1',1''-(methoxysilylidyne)tris-;Silane, methoxytriphenyl-;EINECS 217-382-1;triphenylmethoxysilane;Methoxy(triphenyl)silane #;C19H18OSi;SCHEMBL49088;C19-H18-O-Si;DTXSID30171358;MFCD00161322;AKOS024334167;AS-65407;M3193;D91620

Chemical Property of Methoxytriphenylsilane

Chemical Property:

• Vapor Pressure: 0.000376mmHg at 25°C
• Melting Point: 54.5-55 °C
• Boiling Point: 327.9°C at 760 mmHg
• Flash Point: 152.6°C
• PSA: 9.23000
• Density: 1.08g/cm³
• LogP: 2.29990
• Solubility.: soluble in Methanol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 290.112691728
• Heavy Atom Count: 21
• Complexity: 253

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methoxytriphenylsilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CO[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Methoxytriphenylsilane

There total 25 articles about Methoxytriphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

methanol (67-56-1) + HSiPh3 (789-25-3) → methoxy-triphenyl-silane (1829-41-0)

Guidance literature:

With potassium hexamethylsilazane; In neat liquid; at 30 ℃; for 2h; chemoselective reaction; Schlenk technique; Inert atmosphere;

DOI:10.1071/CH16537

Reference yield: 94.0%

methanol (67-56-1) + N-cyclohexyl(triphenylsilyl)methaneamide (1256450-18-6) → methoxy-triphenyl-silane (1829-41-0)

Guidance literature:

In ⁽²⁾H₈-toluene; at 180 ℃; for 1h; Sealed tube;

DOI:10.1039/c0dt00323a

Reference yield: 92.0%

C--N-(triphenylsilyl)nitrilimine (116889-37-3) → methoxy-triphenyl-silane (1829-41-0) + diazomethane (113597-81-2)

Guidance literature:

With methanol; Yields of byproduct given;

upstream raw materials:

diazomethane

triphenylhydroxysilane

Triphenylsilyl chloride

sodium methylate

Downstream raw materials:

tetraphenylsilane

hexaphenyldisilane

1,1,1-trimethyl-2,2,2-triphenyldisilane

Triethylsilanol

Refernces

• 1、 Sormunen, Pekka,Iiskola, Eero,Vaehaesarja, Eila,Pakkanen, Tuula T.,Pakkanen, Tapani A.. "MODIFICATION OF OLEFIN POLYMERIZATION CATALYSTS II. A 29Si NMR STUDY ON THE COMPLEXATION OF SILYL ETHERS WITH TRIETHYLALUMINIUM". . p. 327 - 332. Retrieved 1987.
• 2、 Cao, Jilei,Lu, Kanghui,Ma, Lishuang,Yang, Xiaona,Zhou, Rong. "Metal-free hydrogen evolution cross-coupling enabled by synergistic photoredox and polarity reversal catalysis". supporting information. p. 8988 - 8994. Retrieved 2021/11/23.
• 3、 Liu, Rongjuan,Wei, Jingjing,Wei, Yanze,Yang, Zhijie,Zhang, Fenghua. "Self-Assembled Open Porous Nanoparticle Superstructures". supporting information. . Retrieved 2021/08/20.