3-(TRICHLOROSTANNYL)METHYLPROPANOATE

Base Information

• Chemical Name: 3-(TRICHLOROSTANNYL)METHYLPROPANOATE
• CAS No.: 59586-13-9
• Molecular Formula: C4H7Cl3O2Sn
• Molecular Weight: 312.167
• Mol file: 59586-13-9.mol

Synonyms:3-(TRICHLOROSTANNYL)METHYLPROPANOATE;CARBOMETHOXYETHYLTRICHLOROTIN;Carbomethoxyethyltrichlorotin [3-(Trichlorostannyl)methylpropanoate];CarbomethoxyethyltrichlorotinTrichlorostannylmethylpropanoate;Nsc297509

Chemical Property of 3-(TRICHLOROSTANNYL)METHYLPROPANOATE

Chemical Property:

• Vapor Pressure: 0.00357mmHg at 25°C
• Melting Point: 69°C
• Boiling Point: 281.4 °C at 760 mmHg
• Flash Point: 124 °C
• PSA: 26.30000
• LogP: 2.20480

Purity/Quality:

99% ^*data from raw suppliers

CARBOMETHOXY ETHYLTRICHLOROTIN 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-(TRICHLOROSTANNYL)METHYLPROPANOATE

There total 2 articles about 3-(TRICHLOROSTANNYL)METHYLPROPANOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro(2-methoxycarbonylethyl)dibutylstannane (79740-12-8) + tin(IV) chloride (7646-78-8) → methyl 3-(trichlorostannyl)propanoate (59586-13-9) + dibutyltin chloride (683-18-1)

Guidance literature:

at 0°C under dry N2; not isolated by IR;

DOI:10.1016/S0022-328X(00)85757-5

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + tin (7440-31-5) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → 2-methoxycarbonylethyltin trichloride (59586-13-9) + bis(2-methoxycarbonylethyl)tin dichloride (10175-01-6)

Guidance literature:

In diethyl ether; reaction of tin, CH3OCOCH=CH2 and dry HCl in ethyl ether, product mixt extd. by warm CHCl3; purifn. of monoester by fractional recrystn.;

DOI:10.1016/0022-328X(83)85115-8

Reference yield: 92.5%

methyl 3-(trichlorostannyl)propanoate (59586-13-9) + ethanol (64-17-5) → C5H9Cl3O2Sn (59586-03-7)

Guidance literature:

In ethanol; byproducts: MeOH; reflux for 2 h; soln. was concd. in vac., solid was recrystd. from CH2Cl2-petroleum ether (30-60 °C) (1:1, v/v), elem. anal.;

DOI:10.1080/00945710009351839

upstream raw materials:

hydrogenchloride

tin

acrylic acid methyl ester

chloro(2-methoxycarbonylethyl)dibutylstannane

Downstream raw materials:

dibutyltin chloride

bis(2-methoxycarbonylethyl)tin dichloride

ClSn(CH₂CH₂CO₂CH₃)3

C₇H₁₃Cl₃O₂Sn

Refernces

• 1、 Burley, Joseph W.,Hutton, Ronald E.. "REDISTRIBUTION REACTIONS OF β-CARBOALKOXYETHYLTIN COMPOUNDS". . p. 165 - 176. Retrieved 2007/10/02.