acrylic acid methyl ester

Base Information

• Chemical Name: acrylic acid methyl ester
• CAS No.: 292638-85-8
• Molecular Formula: C₄H₆O₂
• Molecular Weight: 86.0904
• Mol file: 292638-85-8.mol

Synonyms:acrylic acid methyl ester

Chemical Property of acrylic acid methyl ester

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of acrylic acid methyl ester

There total 223 articles about acrylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.5%

methanol (67-56-1) + acrolein (107-02-8,25068-14-8) → 3,3-dimethoxyprop-1-ene (6044-68-4) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3)

Guidance literature:

With oxygen; Pd₅-Bi₂-Fe₁/⁽¹⁰⁰⁾SiO₂-MgO; for 4h;

Reference yield: 45.0%

methanol (67-56-1) + acetic acid (64-19-7,77671-22-8) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + acetic acid methyl ester (79-20-9) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + acrylic acid (79-10-7)

Guidance literature:

With oxygen; V-Ti-P oxide; at 390 ℃; Product distribution; other temperatures, various oxygen and methanol concentrations;

DOI:10.1246/bcsj.63.199

Reference yield: 42.0%

methanol (67-56-1) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + acetaldehyde (75-07-0,9002-91-9) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + acetone (67-64-1) + acrylic acid (79-10-7)

Guidance literature:

With oxygen; CoMoTeO; V-W-Mo-O; silica gel; In gas; at 360 ℃; Product distribution; two catalytic beds - one reactor; other catalysts (Ni-Co-Fe-Bi-K-P-Mo-O/SiO₂, etc.); effect of the composition of the gas mixture (propene/air, propene/air/water, methanol/nitrogen, methanol/air);

upstream raw materials:

methanol

formaldehyd

acetic acid methyl ester

3-Methoxypropionic acid

Downstream raw materials:

1-(2-Methoxycarbonylethyl)aziridine

methyl 3-(pyrrolidin-1-yl)propanoate

methyl 4,5-dihydro-1H-pyrazole-3-carboxylate

1H-pyrazole-3-carboxylic acid

Refernces

• 1、 Finze, Maik,Reybuck, Sarah E.,Waymouth, Robert M.. "Propylene polymerization with 1,2′-bridged bis(indenyl)zirconium dichlorides". . p. 9325 - 9334. Retrieved 2003.
• 2、 Schultz, Arthur G.,Ravichandran, Ramanathan. "ON THE REACTIVITY OF 3,4-DIMETHOXYCARBONYL-2-PYRAZOLINES WITH DIMETHYL ACETYLENEDICARBOXYLATE". . p. 1771 - 1774. Retrieved 1981.
• 3、 Wolfe, Justin M.,Bernskoetter, Wesley H.. "Reductive functionalization of carbon dioxide to methyl acrylate at zerovalent tungsten". . p. 10763 - 10768. Retrieved 2012.
• 4、 Wang, Yanan,Lang, Xuewei,Zhao, Guoqing,Chen, Huanhui,Fan, Yiwei,Yu, Linqing,Ma, Xiuxiu,Zhu, Zhirong. "Preparation of Cs-La-Sb/SiO2 catalyst and its performance for the synthesis of methyl acrylate by aldol condensation". . p. 32826 - 32834. Retrieved 2015.
• 5、 Feng, Xinzhen,Sun, Bo,Yao, Yao,Su, Qin,Ji, Weijie,Au, Chak-Tong. "Renewable production of acrylic acid and its derivative: New insights into the aldol condensation route over the vanadium phosphorus oxides". . p. 132 - 141. Retrieved 2014.
• 6、 Ratchford,Fisher. "-". . p. 382. Retrieved 1945.
• 7、 Wang, Gang,Li, Zengxi,Li, Chunshan,Zhang, Suojiang. "Unraveling the cation and anion effects and kinetics for ionic liquid catalyzed direct synthesis of methyl acrylate under mild conditions". . p. 7913 - 7923. Retrieved 2020.
• 8、 Oliveira, Rafael L.,Kiyohara, Pedro K.,Rossi, Liane M.. "Clean preparation of methyl esters in one-step oxidative esterification of primary alcohols catalyzed by supported gold nanoparticles". . p. 1366 - 1370. Retrieved 2009.
• 9、 Ai. "The effects of the reaction variables on the yields of acrylic acid and methyl acrylate in the reaction of acetic acid with methanol in the presence of oxygen". . p. 199 - 202. Retrieved 1990.
• 10、 Tan, Kok H.,Xu, Wenjing,Stefka, Simon,Demco, Dan E.,Kharandiuk, Tetiana,Ivasiv, Volodymyr,Nebesnyi, Roman,Petrovskii, Vladislav S.,Potemkin, Igor I.,Pich, Andrij. "Selenium-Modified Microgels as Bio-Inspired Oxidation Catalysts". . p. 9791 - 9796. Retrieved 2019.