Methyl 3-methyl-2-butenyl ether

Base Information

• Chemical Name: Methyl 3-methyl-2-butenyl ether
• CAS No.: 22093-99-8
• Molecular Formula: C6H12 O
• Molecular Weight: 100.161
• Hs Code.: 2909199090
• Mol file: 22093-99-8.mol

Synonyms:Ether,methyl 3-methyl-2-butenyl (8CI); 1-Methoxy-3-methyl-2-butene;3-Methyl-2-butenyl methyl ether; Methyl 3-methyl-2-butenyl ether; Methyl prenylether; NSC 245159

Chemical Property of Methyl 3-methyl-2-butenyl ether

Chemical Property:

• Vapor Pressure: 53.3mmHg at 25°C
• Boiling Point: 94.8°Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: 0.786g/cm³
• LogP: 1.59900

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl 3-methyl-2-butenyl ether

There total 20 articles about Methyl 3-methyl-2-butenyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

3-methyl-2-buten-1-ol (556-82-1) + methyl iodide (74-88-4) → methyl-(3-methyl-but-2-enyl)-ether (22093-99-8)

Guidance literature:

With silver(l) oxide; at 45 ℃; for 6h;

DOI:10.1080/00397919508011412

Reference yield: 46.0%

sodium methylate (124-41-4) + prenyl bromide (870-63-3) → methyl-(3-methyl-but-2-enyl)-ether (22093-99-8) + 3-methoxy-3-methyl-1-butene (40426-44-6)

Guidance literature:

In methanol; for 0.5h;

DOI:10.1021/jo00392a039

Reference yield: 34.0%

methanol (67-56-1) + prenyl bromide (870-63-3) → methyl-(3-methyl-but-2-enyl)-ether (22093-99-8)

Guidance literature:

With sodium; for 45h;

DOI:10.1002/oms.1210180109

upstream raw materials:

methanol

2-methyl-3-buten-2-ol

(4-chloro-3-methyl-but-2-enyl)-methyl ether

sodium methylate

Downstream raw materials:

Prenyltrimethylsilane

<3-Hydroxy-3-methyl-2-(4-methylphenylsulfonylamino)butyl>methylether

1-(ethoxycarbonyl)-2-ethyl-3,3-dimethylaziridine

Methyl isobutyl carbinol

Refernces

• 1、 Bogdanov,Belov. "". . . Retrieved 1979.
• 2、 Harris, Robert J.,Carden, Robert G.,Duncan, Alethea N.,Widenhoefer, Ross A.. "Kinetics and Mechanism of the Gold-Catalyzed Intermolecular Hydroalkoxylation of Allenes with Alcohols". . p. 8941 - 8952. Retrieved 2018/09/06.
• 3、 Tsaconas, Michael,Prager, Rolf H.,Millan, David S.. "Intramolecular rearrangements of but-3-enoic esters". . p. 435 - 437. Retrieved 2007/10/03.