Tetrabutylammonium permanganate

Base Information

• Chemical Name: Tetrabutylammonium permanganate
• CAS No.: 35638-41-6
• Molecular Formula: C16H36MnNO4
• Molecular Weight: 361.404
• Hs Code.: 2923900090
• DSSTox Substance ID: DTXSID30189150
• Mol file: 35638-41-6.mol

Synonyms:tetrabutylammonium permanganate

Chemical Property of Tetrabutylammonium permanganate

Chemical Property:

• PSA: 50.75000
• LogP: 4.63390
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 12
• Exact Mass: 361.202477
• Heavy Atom Count: 22
• Complexity: 212

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[O-][Mn](=O)(=O)=O

Technology Process of Tetrabutylammonium permanganate

There total 2 articles about Tetrabutylammonium permanganate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

potassium permanganate (7722-64-7) + tetrabutylammomium bromide (1643-19-2) → tetra-n-butylammonium permanganate (35638-41-6)

Guidance literature:

In water; pptn. on org. compd. soln. addn. dropwise (stirring) to Mn-salt soln.; ppt. filtration, drying at room temp.;

DOI:10.1021/jp991009u

Reference yield:

potassium permanganate (7722-64-7) + tetrabutyl-ammonium chloride (1112-67-0) → tetra-n-butylammonium permanganate (35638-41-6)

Guidance literature:

Reference yield: 85.0%

2-Picolinic acid (98-98-6) + tetra-n-butylammonium permanganate (35638-41-6) + Mn(2+)*2C2H5COO(1-)*4H2O=Mn(C2H5COO)2*4H2O → N(C4H9)4(1+)*[Mn4O2(C2H5COO)7(C5H4NCOO)2](1-)*0.5H2O=N(C4H9)4Mn4O2(O2CC2H5)7(C5H4NCOO)2*0.5H2O

Guidance literature:

With NBu₄ClO₄; In water; propionic acid; acetonitrile; soln. of Mn-salt in H2O was added to soln. of picolinic acid and NBu4ClO4 in propionic acid, NBu4MnO4 in MeCN was added, stirred for 3 h, Et2O was added; filtered, washed with Et2O, dried in air; elem. anal.;

DOI:10.1021/ic0105617

upstream raw materials:

potassium permanganate

tetrabutyl-ammonium chloride

tetrabutylammomium bromide

Downstream raw materials:

2-(3-trifluoromethoxyphenyl)-5-carboxy pyridine

3-acetyloxymethylbenzoic acid

3,4-Bis(phenylmethoxy)-2,6-pyridinedicarboxylic acid, 6-(phenylmethyl) ester

manganese(picolinate)3(OH₂)

Refernces

• 1、 Brock, Stephanie L.,Sanabria, Maria,Suib, Steven L.,Urban, Volker,Thiyagarajan, Pappannan,Potter, Donald I.. "Particle size control and self-assembly processes in novel colloids of nanocrystalline manganese oxide". . p. 7416 - 7428. Retrieved 1999.
• 2、 -. "Cholic acid derivative and application thereof in lowering cholesterol". Paragraph 0455-0456. . Retrieved 2021/10/30.