1,3,5-Benzenetriphosphonic acid

Base Information

• Chemical Name: 1,3,5-Benzenetriphosphonic acid
• CAS No.: 4672-29-1
• Molecular Formula: C₆H₉O₉P₃
• Molecular Weight: 318.053
• Mol file: 4672-29-1.mol

Synonyms:

Chemical Property of 1,3,5-Benzenetriphosphonic acid

Chemical Property:

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3,5-Benzenetriphosphonic acid

There total 5 articles about 1,3,5-Benzenetriphosphonic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.4%

hexamethyl (benzene-1,3,5-triyl)tris[phosphonate] (449764-33-4) → (benzene-1,3,5-triyl)tris[phosphonic acid] (4672-29-1)

Guidance literature:

With hydrogenchloride; In water; for 10h; Heating;

DOI:10.1002/1522-2675(200204)85:4<1140::AID-HLCA1140>3.0.CO;2-X

Reference yield: 92.0%

hexaethyl benzene-1,3,5-tris(phosphonate) (99624-20-1) → (benzene-1,3,5-triyl)tris[phosphonic acid] (4672-29-1)

Guidance literature:

With hydrogenchloride; water; for 12h;

DOI:10.1039/c3dt32744b

Reference yield: 92.0%

1,3,5-trisbromobenzene (626-39-1) → (benzene-1,3,5-triyl)tris[phosphonic acid] (4672-29-1)

Guidance literature:

1,3,5-trisbromobenzene; With nickel dibromide; at 70 - 180 ℃; Inert atmosphere;

With triethyl phosphite; for 3h; Inert atmosphere;

DOI:10.1039/c3ta12476b

upstream raw materials:

hexamethyl (benzene-1,3,5-triyl)tris[phosphonate]

1,3,5-tris(diisopropyl phosphonate)benzene

1,3,5-trichlorobenzene

hexaethyl benzene-1,3,5-tris(phosphonate)

Refernces

• 1、 Kondo, Atsushi,Satomi, Tokuya,Azuma, Kanami,Takeda, Rie,Maeda, Kazuyuki. "New layered copper 1,3,5-benzenetriphosphonates pillared with N-donor ligands: their synthesis, crystal structures, and adsorption properties". . p. 12717 - 12725. Retrieved 2015.
• 2、 Barbee, Derek,Barron, Andrew R.. "Scalable synthesis of multi-substituted aryl-phosphonates: Exploring the limits of isoretical expansion and the synthesis of new triazene-based phosphonates". . p. 231 - 244. Retrieved 2020/01/03.
• 3、 Pramanik, Malay,Shieh, Fa-Kuen,Alshehri, Saad M.,Alothman, Zeid Abdullah,Wu, Kevin C.-W.,Yamauchi, Yusuke. "Template-free synthesis of nanoporous gadolinium phosphonate as a magnetic resonance imaging (MRI) agent". . p. 42762 - 42767. Retrieved 2015/05/27.