hexaethyl benzene-1,3,5-tris(phosphonate)

Base Information

• Chemical Name: hexaethyl benzene-1,3,5-tris(phosphonate)
• CAS No.: 99624-20-1
• Molecular Formula: C₁₈H₃₃O₉P₃
• Molecular Weight: 486.376
• Mol file: 99624-20-1.mol

Synonyms:hexaethyl benzene-1,3,5-tris(phosphonate)

Chemical Property of hexaethyl benzene-1,3,5-tris(phosphonate)

Chemical Property:

Purity/Quality:

95%-98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hexaethyl benzene-1,3,5-tris(phosphonate)

There total 2 articles about hexaethyl benzene-1,3,5-tris(phosphonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

1,3,5-trisbromobenzene (626-39-1) + triethyl phosphite (122-52-1) → hexaethyl benzene-1,3,5-tris(phosphonate) (99624-20-1)

Guidance literature:

With nickel dibromide; at 180 ℃; for 9h; Inert atmosphere;

DOI:10.1039/c3dt32744b

Reference yield:

diethyl phosphonoacetaldehyde diethyl acetal (7598-61-0) → hexaethyl benzene-1,3,5-tris(phosphonate) (99624-20-1)

Guidance literature:

With hydrogenchloride; hydroquinone;

Reference yield: 92.0%

hexaethyl benzene-1,3,5-tris(phosphonate) (99624-20-1) → (benzene-1,3,5-triyl)tris[phosphonic acid] (4672-29-1)

Guidance literature:

With hydrogenchloride; water; for 12h;

DOI:10.1039/c3dt32744b

upstream raw materials:

diethyl phosphonoacetaldehyde diethyl acetal

1,3,5-trisbromobenzene

triethyl phosphite

Downstream raw materials:

(benzene-1,3,5-triyl)tris[phosphonic acid]

Refernces

• 1、 Luca, Vittorio,Tejada, Juan J.,Vega, Daniel,Arrachart, Guilhem,Rey, Cyrielle. "Zirconium(IV)-Benzene Phosphonate Coordination Polymers: Lanthanide and Actinide Extraction and Thermal Properties". supporting information. p. 7928 - 7943. Retrieved 2016/08/24.
• 2、 Pramanik, Malay,Bhaumik, Asim. "Organic-inorganic hybrid supermicroporous iron(III) phosphonate nanoparticles as an efficient catalyst for the synthesis of biofuels". . p. 8507 - 8514. Retrieved 2013/07/26.