Chlorodifluoroamine

Base Information

• Chemical Name: Chlorodifluoroamine
• CAS No.: 13637-87-1
• Molecular Formula: ClF2N
• Molecular Weight: 87.4565
• DSSTox Substance ID: DTXSID10159770
• Nikkaji Number: J95.129C
• Wikidata: Q4162500
• Mol file: 13637-87-1.mol

Synonyms:Chlorodifluoroamine;Chlorodifluoroammonia;Chlorodifluoramine;Difluorochloroamine;Nitrogen chloride difluoride;13637-87-1;Nitrogen chloride fluoride (nclf2);chlorodifluoroazane;chloro(difluoro)amine;NCl2F;chloridodifluoridonitrogen;Nitrogen chloride fluoride;N-Chloro-N,N-difluoroamine #;CHEBI:37383;DTXSID10159770;Q4162500

Chemical Property of Chlorodifluoroamine

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: 1.506g/cm³
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 86.9687330
• Heavy Atom Count: 4
• Complexity: 13.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N(F)(F)Cl

Technology Process of Chlorodifluoroamine

There total 5 articles about Chlorodifluoroamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

tetrafluorohydrazine (10036-47-2) + oxalyl dichloride (79-37-8) → phosgene (75-44-5) + chlorodifluoroamine (13637-87-1) + dinitrogen difluoride (10578-16-2) + fluoroformyl chloride (353-49-1) + difluorocarbamoyl chloride (16847-30-6)

Guidance literature:

other Radiation; UV photolysis, 6h, ratio of educts: (ClCO)2 112 Torr, N2F4 168 Torr; fractionated condensation, gaschromy.;

Reference yield: 30.0%

sodium azide + chlorine (7782-50-5) + fluorine (7782-41-4) → tetrafluorohydrazine (10036-47-2) + chlorodifluoroamine (13637-87-1) + dinitrogen difluoride (10578-16-2)

Guidance literature:

In neat (no solvent); byproducts: N2, N2O, NOCl; at 23 - 30°C;;

Reference yield:

difluoroamine (10405-27-3) + chlorine trifluoride (7790-91-2) → tetrafluorohydrazine (10036-47-2) + chlorodifluoroamine (13637-87-1) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8)

Guidance literature:

In neat (no solvent); at -78°CC;;

DOI:10.1021/ic50060a045

upstream raw materials:

chlorine trifluoride

difluoroamine

chlorine

fluorine

Downstream raw materials:

hydrogenchloride

nitrogen monofluoride

hydrogen fluoride

nitrogen trifluoride

Refernces

• 1、 Wright, Kenneth J.,Shreeve, Jean'ne M.. "Some chemistry of difluoraminocarbonyl chloride. A new route to perfluorourea". . p. 77 - 80. Retrieved 2007/10/12.
• 2、 Cauble, Ronald L.,Cady, George H.. "New preparation of difluorocarbamyl chloride, ClC(O)NF2". . p. 2117 - 2117. Retrieved 2008/10/08.