Ammonium, tetramethyl-, thiocyanate

Base Information

• Chemical Name: Ammonium, tetramethyl-, thiocyanate
• CAS No.: 15597-46-3
• Molecular Formula: C5H12N2S
• Molecular Weight: 132.23
• DSSTox Substance ID: DTXSID10166005
• Mol file: 15597-46-3.mol

Synonyms:Tetramethylammonium thiocyanate;AMMONIUM, TETRAMETHYL-, THIOCYANATE;N,N,N-Trimethylmethanaminium thiocyanate;Methanaminium, N,N,N-trimethyl-, thiocyanate;15597-46-3;tetramethylazanium thiocyanate;C4H12N.CNS;SCHEMBL36788;C4-H12-N.C-N-S;DTXSID10166005;LS-19071

Chemical Property of Ammonium, tetramethyl-, thiocyanate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 132.07211956
• Heavy Atom Count: 8
• Complexity: 50.4

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[N+](C)(C)C.C(#N)[S-]

Technology Process of Ammonium, tetramethyl-, thiocyanate

There total 1 articles about Ammonium, tetramethyl-, thiocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + acetonitrile (75-05-8,26809-02-9) + trimethylamine (75-50-3) → methylthiol (74-93-1) + dimethylsulfide (75-18-3) + tetramethylammonium thiocyanate (15597-46-3)

Guidance literature:

at 200 - 210 ℃;

Reference yield: 91.0%

K2[Co(SCN)4] + tetramethylammonium thiocyanate (15597-46-3) → (NMe4)2[Co(NCS)4]

Guidance literature:

In ethanol; Inert atmosphere;

DOI:10.1021/ic401558f

Reference yield: 80.0%

praseodymium(III) thiocyanate + tetramethylammonium thiocyanate (15597-46-3) → 5N(CH3)4(1+)*Pr(NCS)8(5-)*2C6H6={(CH3)4N}5{Pr(NCS)8}*2C6H6

Guidance literature:

With benzene; In methanol; leaving a soln. of tetramethylammonium thiocyanate and Pr thiocyanate in benzene vapor (several days), crystn.;

DOI:10.1246/bcsj.63.620

upstream raw materials:

methanol

acetonitrile

trimethylamine

Downstream raw materials:

methyl thiocyanate

trimethylamine

Tetramethylammoniumphenyl-dithiocyanatotellurat(II)

formic acid