NNN'N'-TETRAETHYLISOPHTHALAMIDE

Base Information

• Chemical Name: NNN'N'-TETRAETHYLISOPHTHALAMIDE
• CAS No.: 13698-87-8
• Molecular Formula: C16H24N2O2
• Molecular Weight: 276.379
• Hs Code.: 2924299090
• Mol file: 13698-87-8.mol

Synonyms:1,3-Benzenedicarboxamide,N,N,N',N'-tetraethyl- (9CI);m-Bis(diethylcarbamoyl)benzene;Isophthalamide, N,N,N',N'-tetraethyl- (6CI,8CI);N,N,N',N'-Tetraethylbenzene-1,3-dicarboxamide;N,N,N',N'-Tetraethylisophthalamide;

Chemical Property of NNN'N'-TETRAETHYLISOPHTHALAMIDE

Chemical Property:

• Melting Point: 86°C
• Refractive Index: 1.5800 (estimate)
• Boiling Point: 455.4 °C at 760 mmHg
• PKA: -1.38±0.70(Predicted)
• Flash Point: 198.2 °C
• PSA: 40.62000
• Density: 1.038 g/cm³
• LogP: 2.65060
• Water Solubility.: 199g/L(30 oC)

Purity/Quality:

98%Min ^*data from raw suppliers

NNN''N''-Tetraethylisophthalamide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of NNN'N'-TETRAETHYLISOPHTHALAMIDE

There total 5 articles about NNN'N'-TETRAETHYLISOPHTHALAMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

triethylamine (121-44-8) + benzene-1,3-dicarbonyl dichloride (99-63-8) → N1,N1,N3,N3-tetraethylisophthalamide (13698-87-8)

Guidance literature:

With B₁₂ complex immobilized on rhodium(III) modified anatase TiO₂; air; In acetonitrile; at 20 ℃; for 3h; Irradiation;

DOI:10.1016/j.jorganchem.2019.121058

Reference yield: 45.0%

1,3-bis-trichloromethyl-benzene (881-99-2) + triethylamine (121-44-8) → N1,N1,N3,N3-tetraethylisophthalamide (13698-87-8)

Guidance literature:

With heptamethyl Coβ-perchlorato-cob(II)yrinate; tetrabutylammonium perchlorate; In acetonitrile; at 20 ℃; for 3h; Electrolysis;

DOI:10.1021/acs.joc.1c00161

Reference yield:

1,3-bis-trichloromethyl-benzene (881-99-2) + diethylamine (109-89-7) → N1,N1,N3,N3-tetraethylisophthalamide (13698-87-8)

Guidance literature:

With heptamethyl Coβ-perchlorato-cob(II)yrinate; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; N-ethyl-N,N-diisopropylamine; In acetonitrile; at 20 ℃; for 3h; Irradiation;

DOI:10.1002/cplu.201800522

upstream raw materials:

diethylamine

benzene-1,3-dicarbonyl dichloride

1,3-bis-trichloromethyl-benzene

triethylamine

Downstream raw materials:

1,3-bis(2-pyridinecarbonyl)benzene

1,3-dipropionyl-benzene

Refernces

• 1、 Shichijo, Keita,Fujitsuka, Mamoru,Hisaeda, Yoshio,Shimakoshi, Hisashi. "Visible light-driven photocatalytic duet reaction catalyzed by the B12-rhodium-titanium oxide hybrid catalyst". supporting information. . Retrieved 2019/12/24.