Thioperoxydiphosphoric acid ([(HO)2P(S)]2S2), tetramethyl ester

Base Information

• Chemical Name: Thioperoxydiphosphoric acid ([(HO)2P(S)]2S2), tetramethyl ester
• CAS No.: 5930-71-2
• Molecular Formula: C4H12 O4 P2 S4
• Molecular Weight: 314.348
• European Community (EC) Number: 227-673-5
• DSSTox Substance ID: DTXSID8064064
• Nikkaji Number: J32.936C
• Wikidata: Q81991214
• Mol file: 5930-71-2.mol

Synonyms:Tetramethyl thioperoxydiphosphate;5930-71-2;EINECS 227-673-5;Bis(O,O-dimethylthiophosphoryl)disulfide;BRN 1798158;Thioperoxydiphosphoric acid, tetramethyl ester;Thioperoxydiphosphoric acid ([(HO)2P(S)]2S2), tetramethyl ester;Thioperoxydiphosphoric acid, O,O,O,O-tetramethyl-;Thioperoxydiphosphoric acid (((HO)2P(S))2S2), tetramethyl ester;Methyl thioperoxydiphosphate (((MeO)2PS)2S2);Thioperoxydiphosphoric acid (((HO)2P(S))2S2), Op,Op,Op',Op'-tetramethyl ester;DTXSID8064064;SCHEMBL11059829;C4H12O4P2S4;C4-H12-O4-P2-S4;Bis(dimethoxyphosphinothioyl) persulfide;LS-152843;Thioperoxydiphosphoric acid (((HO)2-P(S))2-S2), tetramethyl ester

Chemical Property of Thioperoxydiphosphoric acid ([(HO)2P(S)]2S2), tetramethyl ester

Chemical Property:

• Vapor Pressure: 0.000282mmHg at 25°C
• Melting Point: 51-52 °C(Solv: hexane (110-54-3))
• Boiling Point: 332.4°C at 760 mmHg
• Flash Point: 154.8°C
• PSA: 171.32000
• Density: 1.482g/cm³
• LogP: 4.70360
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 7
• Exact Mass: 313.90936755
• Heavy Atom Count: 14
• Complexity: 218

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COP(=S)(OC)SSP(=S)(OC)OC

Technology Process of Thioperoxydiphosphoric acid ([(HO)2P(S)]2S2), tetramethyl ester

There total 10 articles about Thioperoxydiphosphoric acid ([(HO)2P(S)]2S2), tetramethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

sodium O,O-dimethyl phosphorodithioate (26377-29-7) → bis(dimethyloxyphosphinothioyl) disulfide (5930-71-2) + ditropenyl (831-18-5)

Guidance literature:

With tropylium cation; 6,7-dihydrodipyrido[1,2-a:2',1'-c]pyrazinedium dication; In acetonitrile; for 6h; Yield given; Irradiation;

DOI:10.1016/S0040-4039(01)81311-3

Reference yield:

O,O-dimethyl phosphorodithioic acid (756-80-9) → bis(dimethyloxyphosphinothioyl) disulfide (5930-71-2)

Guidance literature:

With benzoyl cyanide; In benzene;

Reference yield:

sodium O,O-dimethyl phosphorodithioate (26377-29-7) → bis(dimethyloxyphosphinothioyl) disulfide (5930-71-2)

Guidance literature:

With iodine; In ethanol; water;

DOI:10.1016/S1386-1425(01)00707-7

upstream raw materials:

O,O-dimethyl phosphorodithioic acid

O,O-dimethyl dithiophosphoric acid S-trimethylsilyl ester

dithiophosphoric acid O,O'-dimethyl ester; deprotonated form

Paraquat

Downstream raw materials:

cis-Propenyl O,O'-Dimethyl Dithiophosphate

Refernces

• 1、 Yordanov, Nicola D.,Ranguelova, Kalina. "Effect of solute-co-ordinating solvent interactions and temperature on the EPR and electronic spectra of bis(dithiophosphato)copper(II)". . p. 1171 - 1180. Retrieved 2007/10/03.
• 2、 Deronzier, Alain. "A PHOTO-INDUCED REACTION BY VISIBLE LIGHT VIA A CHARGE TRANSFER COMPLEX". . p. 2867 - 2868. Retrieved 2007/10/02.