Ethylene-d3

Base Information

• Chemical Name: Ethylene-d3
• CAS No.: 2680-01-5
• Molecular Formula: C2H4
• Molecular Weight: 31.0299
• European Community (EC) Number: 694-324-5
• DSSTox Substance ID: DTXSID80181306
• Nikkaji Number: J567.155H
• Mol file: 2680-01-5.mol

Synonyms:Ethylene-d3;2680-01-5;1,1,2-trideuterioethene;d3-ethylene;Ethene-d3;CD2=CDH;DTXSID80181306;Ethylene-d3, 98 atom % D, 99% (CP)

Chemical Property of Ethylene-d3

Chemical Property:

• Vapor Pressure: 43300mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 0.534g/cm³
• LogP: 0.80220
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 31.0501303654
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

99%, ^*data from raw suppliers

ETHYLENE-D3 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F+
• Statements: 12-67
• Safety Statements: 9-16-33-46-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C
• Isomeric SMILES: [2H]C=C([2H])[2H]

Technology Process of Ethylene-d3

There total 17 articles about Ethylene-d3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-butane-1,1,1,4,4,4-d6 (13183-67-0) → methane (558-20-3) + ethylene-d3 (2680-01-5) + 1,1,4,4,4-pentadeuterio-but-1-ene (36789-12-5)

Guidance literature:

With chromium oxide cation; Product distribution; Mechanism;

DOI:10.1021/ja00284a011

Reference yield:

n-butane-1,1,1,4,4,4-d6 (13183-67-0) → methane-d2 (676-55-1) + Monodeuteromethan (676-49-3) + methane-d3 (676-80-2) + ethene (74-85-1) + methane (558-20-3) + ethylene-d3 (2680-01-5)

Guidance literature:

With titanium⁽¹⁺⁾; Product distribution; reaction with V⁺ also investigated;

DOI:10.1021/ja00284a012

Reference yield:

diiodomethane (75-11-6) + paraformaldehyde-d2 (1664-98-8,43094-80-0) → ethene (74-85-1) + ethylene-1,1-d2 (6755-54-0) + ethylene-d3 (2680-01-5) + Ethylene-d4 (683-73-8,25549-98-8)

Guidance literature:

With vanadium; Heating;

upstream raw materials:

1,1,2,2-tetradeuterio-ethyl

3,3,6,6-d4-cyclohexene

bromoethane-1,1,2,2-d4

n-butane-1,1,1,4,4,4-d₆

Refernces

• 1、 Yang, Michael X.,Bent, Brian E.. "H and D atom addition to ethylene on Cu(100): Absence of ethyl H/D shift and decomposition". . p. 822 - 832. Retrieved 2007/10/03.
• 2、 Lifshitz, Assa,Bidani, Menashe,Agranat, Ahuva,Suslensky, Aya. "Thermal Reactions of Pyrrolidine at Elevated Temperatures. Studies with a Single-Pulse Shock Tube". . p. 6043 - 6048. Retrieved 2007/10/02.