Technology Process of [10-(Hydroxymethyl)-13-methyl-3-oxo-1,2,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl] benzoate
There total 6 articles about [10-(Hydroxymethyl)-13-methyl-3-oxo-1,2,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl] benzoate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.8 g / lithium tri-tert-butoxyaluminium hydride / tetrahydrofuran / 0.67 h / Ambient temperature
2: 1.8 g / pyridine / 24 h / Ambient temperature
3: 18.1 g / KOH / methanol; tetrahydrofuran / 1.5 h / 16 °C
4: 12 g / CrO3-pyridine / 6 h / Ambient temperature
5: 6.7 g / Zn / acetic acid / 0.67 h / 100 °C
With
pyridine; potassium hydroxide; lithium tri(t-butoxy)aluminum hydride; chromium trioxide-pyridine complex; zinc;
In
tetrahydrofuran; methanol; acetic acid;
DOI:10.1135/cccc19822423
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 18.1 g / KOH / methanol; tetrahydrofuran / 1.5 h / 16 °C
2: 12 g / CrO3-pyridine / 6 h / Ambient temperature
3: 6.7 g / Zn / acetic acid / 0.67 h / 100 °C
With
potassium hydroxide; chromium trioxide-pyridine complex; zinc;
In
tetrahydrofuran; methanol; acetic acid;
DOI:10.1135/cccc19822423