Dichloro(cycloocta-1,5-diene)ruthenium(II)

Base Information

• Chemical Name: Dichloro(cycloocta-1,5-diene)ruthenium(II)
• CAS No.: 50982-12-2
• Molecular Formula: C8H12Cl2Ru
• Molecular Weight: 280.159
• Hs Code.: 28439000
• European Community (EC) Number: 256-889-2
• Mol file: 50982-12-2.mol

Synonyms:50982-12-2;Dichloro(cycloocta-1,5-diene)ruthenium(II);Dichloro(1,5-cyclooctadiene)ruthenium(II);(1,5-Cyclooctadiene)ruthenium(II) chloride;MFCD00171304;Dichloro(1,5-CYCLOOCTADIENE)RUTHENIUM (II);(1Z,5Z)-cycloocta-1,5-diene;dichlororuthenium;C8H12Cl2Ru;C8-H12-Cl2-Ru;1,5-cyclooctadiene ruthenium dichloride (II);EINECS 256-889-2;[rucl2(cod)]n;Dichloro((1,2,5,6-eta)-cycloocta-1,5-diene)ruthenium;Dichloro[(1,2,5,6-eta)-cycloocta-1,5-diene]ruthenium;SCHEMBL40687;DMRVBCXRFYZCPR-PHFPKPIQSA-L;AKOS024258168;cycloocta-1,5-diene;AS-65340;BP-12210;CS-0015978;A871404;dichloro(cycloocta-1,5-diene)ruthenium(ii), AldrichCPR

Chemical Property of Dichloro(cycloocta-1,5-diene)ruthenium(II)

Chemical Property:

• Appearance/Colour: brown powder
• Vapor Pressure: 4.25mmHg at 25°C
• Melting Point: 293 °C
• Boiling Point: 153.5 °C at 760 mmHg
• Flash Point: 31.7 °C
• PSA: 0.00000
• LogP: 4.05180
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility.: Insoluble in all solvent tried
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 279.935946
• Heavy Atom Count: 11
• Complexity: 75.4

Purity/Quality:

98% ^*data from raw suppliers

Dichloro(cycloocta-1,5-diene)ruthenium(II)Polymer ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,Xn
• Statements: 52/53-22
• Safety Statements: 61

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CC=CCCC=C1.Cl[Ru]Cl
• Isomeric SMILES: C1/C=C\CC/C=C\C1.Cl[Ru]Cl
• Uses: Dichloro(cycloocta-1,5-diene)ruthenium(II) Polymer is a catalytic reagent that is used for ruthenium-catalyzed transfer hydrogenation reactions with dimethylamine borane for reduction of ketones, aldehydes, imines, oximes, nitriles, nitroarenes and alkenes.

Technology Process of Dichloro(cycloocta-1,5-diene)ruthenium(II)

There total 2 articles about Dichloro(cycloocta-1,5-diene)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

rhodium(III) chloride hydrate + cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → dichloro(1,5-cyclooctadiene)ruthenium(II) (50982-12-2,50982-13-3)

Guidance literature:

In ethanol; for 72h; Inert atmosphere; Reflux;

DOI:10.1039/c6dt03792e

Reference yield:

1,5-cis,cis-cyclooctadiene (1552-12-1,111-78-4) + ruthenium(III) chloride trihydrate → dichloro(1,5-cyclooctadiene)ruthenium(II) (50982-12-2,50982-13-3)

Guidance literature:

In ethanol; at 85 ℃; for 5h; Inert atmosphere;

Reference yield: 92.0%

cyclooctadiene ruthenium(II) dichloride (50982-12-2) + 1,4-di(diphenylphosphino)-butane (7688-25-7) + (5-methylpyrazine-2-yl)methylamine (132664-85-8) → cis-RuCl2(1,4-bis(diphenylphosphino)butane)(2-aminomethyl-5-methylpyrazine)

Guidance literature:

cyclooctadiene ruthenium(II) dichloride; 1,4-di(diphenylphosphino)-butane; In N,N-dimethyl-formamide; at 120 - 125 ℃; for 1h;

(5-methylpyrazine-2-yl)methylamine; In N,N-dimethyl-formamide; at 120 - 125 ℃; for 0.166667h; Temperature;

upstream raw materials:

1,5-cis,cis-cyclooctadiene

cyclo-octa-1,5-diene

Downstream raw materials:

(3S)-3-[(1S)-2-(benzyloxy)-1-hydroxyethyl]-4,5-dihydrofuran-2(3H)-one

Λ-Ru(OOC-t-Bu)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)

Ru(H)2(dppe)2

Δ-Ru(OOCCH3)2((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)

Refernces

• 1、 Poulsen, Bj?rn C.,Estalayo-Adrián, Sandra,Blasco, Salvador,Bright, Sandra A.,Kelly, John M.,Williams, D. Clive,Gunnlaugsson, Thorfinnur. "Luminescent ruthenium polypyridyl complexes with extended 'dppz' like ligands as DNA targeting binders and cellular agents". supporting information. p. 18208 - 18220. Retrieved 2016/11/25.