(3-Chloropropyl)trimethylsilane

Base Information

• Chemical Name: (3-Chloropropyl)trimethylsilane
• CAS No.: 2344-83-4
• Molecular Formula: C6H15ClSi
• Molecular Weight: 150.724
• Hs Code.: 2931900090
• European Community (EC) Number: 219-059-0
• UNII: ZQ55NC95GS
• DSSTox Substance ID: DTXSID6062331
• Nikkaji Number: J213.200A
• Wikidata: Q81989974
• Mol file: 2344-83-4.mol

Synonyms:(3-Chloropropyl)trimethylsilane;2344-83-4;3-Chloropropyltrimethylsilane;Silane, (3-chloropropyl)trimethyl-;3-chloropropyl(trimethyl)silane;EINECS 219-059-0;2744-83-4;MFCD00045299;chloropropyltrimethylsilane;chloropropyl trimethyl silane;ZQ55NC95GS;3-Trimethylsilylpropyl chloride;SCHEMBL1220821;DTXSID6062331;(3-chloro-propyl)-trimethyl-silane;1-Chloro-3-(trimethylsilyl)propane;CAA34483;AKOS006221243;AS-77885;(3-Chloropropyl)trimethylsilane, >=97.0%;CS-0199377;FT-0604707;E78042;EN300-111896;A851551;J-015110

Chemical Property of (3-Chloropropyl)trimethylsilane

Chemical Property:

• Vapor Pressure: 4.77mmHg at 25°C
• Melting Point: < 0 °C
• Refractive Index: n20/D 1.431
• Boiling Point: 151 °C at 760 mmHg
• Flash Point: 30.5 °C
• PSA: 0.00000
• Density: 0.862 g/cm³
• LogP: 2.95350
• Water Solubility.: Not miscible in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 150.0631547
• Heavy Atom Count: 8
• Complexity: 56

Purity/Quality:

95% ^*data from raw suppliers

(3-Chloropropyl)trimethylsilane ≥97.0% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Si](C)(C)CCCCl
• Uses: (3-Chloropropyl)trimethylsilane used in the preparation of: 8-(3-trimethylsilylpropoxy)quinolone under phase transfer catalytic conditions, 5-trimethylsilyl pentanol, N-(tri-methylsilylalkyl)diamines.

Technology Process of (3-Chloropropyl)trimethylsilane

There total 7 articles about (3-Chloropropyl)trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

(3-chloropropyl)triethoxysilane (5089-70-3) + methyllithium (917-54-4) → (3-chloropropyl)trimethylsilane (2344-83-4)

Guidance literature:

In diethyl ether; for 32h; Heating;

DOI:10.1016/0022-328X(84)85094-9

Reference yield:

dichloro(3-chloropropyl)methylsilane (7787-93-1) + methylmagnesium bromide (75-16-1) → (3-chloropropyl)trimethylsilane (2344-83-4)

Guidance literature:

In diethyl ether;

DOI:10.1021/ja01499a031

Reference yield:

dichloro(3-chloropropyl)methylsilane (7787-93-1) → (3-chloropropyl)trimethylsilane (2344-83-4)

Guidance literature:

DOI:10.1021/ja01568a028

upstream raw materials:

dichloro(3-chloropropyl)methylsilane

methylmagnesium bromide

3-chloropropyltrichlorosilane

methylmagnesium chloride

Downstream raw materials:

(3-Acetoxy-propyl)-trimethyl-silan

(3-iodopropyl)trimethylsilane

1,3-bis(trimethylsilyl)propane

4-trimethylsilanyl-butyric acid

Refernces

• 1、 Hu, Chunye,He, Ji-Gang,O'Brien, D. H.,Irgolic, K. J.. "N-ETHYLENEDIAMINES". . p. 31 - 38. Retrieved 2007/10/02.