Trichloro(3-chloropropyl)silane

Base Information

• Chemical Name: Trichloro(3-chloropropyl)silane
• CAS No.: 2550-06-3
• Molecular Formula: C3H6Cl4Si
• Molecular Weight: 211.978
• Hs Code.: 29319090
• European Community (EC) Number: 219-844-8
• NSC Number: 139831
• UNII: R1554E15C2
• DSSTox Substance ID: DTXSID4027492
• Nikkaji Number: J192.043J
• Wikidata: Q27287647
• Mol file: 2550-06-3.mol

Synonyms:3-Chloropropyltrichlorosilane;2550-06-3;Trichloro(3-chloropropyl)silane;(3-Chloropropyl)trichlorosilane;Chloropropyltrichlorosilane;Silane, trichloro(3-chloropropyl)-;Silane, 3-chloropropyltrichloro-;Silane, trichloro(chloropropyl)-;Trichloro-(3-chloro-propyl)-silane;(.gamma.-Chloropropyl)trichlorosilane;EINECS 219-844-8;NSC 139831;NSC-139831;R1554E15C2;C3H6Cl4Si;CC3291;NSC139831;CPTCS;Cl3SiCH2CH2CH2Cl;g-chloropropyltrichlorosilane;SCHEMBL133244;Trichloro-3-chloropropylsilane;3-chloropropyl-trichloro-silane;gamma-chloropropyltrichlorosilane;DTXSID4027492;UNII-R1554E15C2;(3-chloropropyl)-trichlorosilane;gamma-chloropropyl trichlorosilane;MFCD00013694;.gamma.-Chloropropyl trichloro silane;AKOS015850550;FS-3965;1-CHLORO-3-(TRICHLOROSILYL)PROPANE;J192.043J;LS-195335;CS-0158359;FT-0634359;EC 219-844-8;EN300-380951;Q27287647

Chemical Property of Trichloro(3-chloropropyl)silane

Chemical Property:

• Appearance/Colour: Colorless clear liquid
• Vapor Pressure: 1.35mmHg at 25°C
• Refractive Index: 1.465
• Boiling Point: 178.3 °C at 760 mmHg
• Flash Point: 69.4 °C
• PSA: 0.00000
• Density: 1.35 g/cm³
• LogP: 3.27060
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 211.896337
• Heavy Atom Count: 8
• Complexity: 58.8

Purity/Quality:

99% ^*data from raw suppliers

3-Chloropropyltrichlorosilane >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 14-34
• Safety Statements: 26-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C[Si](Cl)(Cl)Cl)CCl

Technology Process of Trichloro(3-chloropropyl)silane

There total 21 articles about Trichloro(3-chloropropyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.6%

3-chloroprop-1-ene (107-05-1) → 3-chloropropyltrichlorosilane (2550-06-3)

Guidance literature:

With tributyl-amine; trichlorosilane; at -30 - 80 ℃; for 3.5h; Temperature;

Reference yield: 73.9%

trichlorosilane (10025-78-2) + 3-chloroprop-1-ene (107-05-1) → tetrachlorosilane (10026-04-7,53609-55-5) + n-propyltrichlorosilane (141-57-1) + 3-chloropropyltrichlorosilane (2550-06-3)

Guidance literature:

With chloroplatinic acid; N,N-dimethyl acetamide; In isopropyl alcohol; at 80 - 135 ℃; for 8h; Reagent/catalyst; Temperature; Catalytic behavior; Autoclave; Industrial scale;

Reference yield: 68.4%

3-chloroprop-1-ene (107-05-1) → n-propyltrichlorosilane (141-57-1) + 3-chloropropyltrichlorosilane (2550-06-3)

Guidance literature:

With trichlorosilane; at 75 - 80 ℃; for 12h;

DOI:10.1016/S0022-328X(00)83695-5

upstream raw materials:

n-propyltrichlorosilane

3-chloroprop-1-ene

isopropyl alcohol

trichlorosilane

Downstream raw materials:

allyltrichlorosilane

trichlorovinylsilane

1-(3-chloropropyl)silatrane

chloro-trimethyl-silane

Refernces

• 1、 Sommer, L. H.,Dorfman, E.,Whitmore, F. C.. "-". . p. 1083 - 1085. Retrieved 1946.
• 2、 -. "Continuous production process and device for γ - chloropropyltrichlorosilane". Paragraph 0060-0091. . Retrieved 2021/09/29.
• 3、 -. "The ligand bidentate phosphine rhodium complex and its manufacturing method, and a hydrosilylation of allyl halide using a rhodium complex compound having a bidentate phosphine (by machine translation)". Paragraph 0047-0048. . Retrieved 2020/09/16.