Sulfur tetrafluoride oxide

Base Information

• Chemical Name: Sulfur tetrafluoride oxide
• CAS No.: 13709-54-1
• Molecular Formula: F4O S
• Molecular Weight: 124.059
• DSSTox Substance ID: DTXSID30160060
• Nikkaji Number: J95.300H
• Wikipedia: Sulfur tetrafluoride oxide,Thionyl tetrafluoride,Thionyl_tetrafluoride
• Wikidata: Q7784685
• Mol file: 13709-54-1.mol

Synonyms:Sulfur tetrafluoride oxide;13709-54-1;Thionyl tetrafluoride;tetrafluoro(oxo)-lambda6-sulfane;SOF4;Sulphur oxide tetrafluoride;Sulfur fluoride oxide (SF4O);SULFURYL OXYTETRAFLUORIDE;DTXSID30160060;MFCD00236740;(SP-5-21)-Sulfur fluoride oxide (SF4O);FT-0694009

Chemical Property of Sulfur tetrafluoride oxide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 36.28000
• Density: g/cm³
• LogP: 2.21020
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 123.96059844
• Heavy Atom Count: 6
• Complexity: 85.2

Purity/Quality:

99%, ^*data from raw suppliers

SULFURYL OXYTETRAFLUORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 26-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

Useful:

• Chemical Classes: Other Classes -> Sulfur Compounds
• Canonical SMILES: O=S(F)(F)(F)F

Technology Process of Sulfur tetrafluoride oxide

There total 23 articles about Sulfur tetrafluoride oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.4%

hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) → fluorosulfonyl fluoride (640723-20-2,2699-79-8,12769-73-2) + thionyl tetrafluoride (173009-97-7,118492-84-5,13709-54-1) + sulfur(VI) hexafluoride (2551-62-4)

Guidance literature:

In hydrogen fluoride; byproducts: OF2; Electrolysis; 16°C, 6-8 Volt,;

Reference yield: 87.0%

sulfur tetrafluoride (7783-60-0) + oxygen (80937-33-3) → thionyl tetrafluoride (173009-97-7,118492-84-5,13709-54-1)

Guidance literature:

With Nitrogen dioxide; at 238 ℃; for 8h; under 25858.1 - 87917.5 Torr; Autoclave;

DOI:10.1002/anie.201712145

Reference yield: 45.0%

bis(pentafluorosulfur) peroxide (12395-41-4) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) → thionyl tetrafluoride (173009-97-7,118492-84-5,13709-54-1) + pentafluorosulfur fluorosulfonate (81439-35-2) + sulfur trioxide (7446-11-9) + thionyl fluoride (7783-42-8) + sulfur(VI) hexafluoride (2551-62-4)

Guidance literature:

byproducts: SiF4, sulfur; other Radiation; photochemical reaction with 253.7 nm radiation, 48 h;

DOI:10.1039/JR9620000771

upstream raw materials:

dinitrogen difluoride

sulfur dioxide

hydrogen fluoride

bis(pentafluorosulfur) peroxide

Downstream raw materials:

fluorosulfonyl fluoride

hydrogen fluoride

fluoride

Sulfate

Refernces

• 1、 -. "THIONYL TETRAFLUORIDE MODIFIED COMPOUNDS AND USES". Page/Page column 34. . Retrieved 2018/06/22.
• 2、 Lu, Norman,Thrasher, Joseph S.,Von Ahsen, Stefan,Willner, Helge,Hnyk, Drahomir,Oberhammer, Heinz. "Pentafluoronitrosulfane, SF5NO2". . p. 1783 - 1788. Retrieved 2008/10/09.