Styryl acetate

Base Information

• Chemical Name: Styryl acetate
• CAS No.: 10521-96-7
• Molecular Formula: C10H10 O2
• Molecular Weight: 162.188
• Hs Code.: 2915390090
• European Community (EC) Number: 234-065-3
• Nikkaji Number: J957.105A,J212.449A
• Mol file: 10521-96-7.mol

Synonyms:Styryl acetate;Ethenol, 2-phenyl-, 1-acetate;EINECS 234-065-3;[(E)-2-phenylethenyl] acetate;(E)-styryl acetate;acetic acid styryl ester;Acetic acid (E)-styryl ester;FMFHUEMLVAIBFI-BQYQJAHWSA-N;1566-67-2

Chemical Property of Styryl acetate

Chemical Property:

• Vapor Pressure: 0.0319mmHg at 25°C
• Boiling Point: 243.6°Cat760mmHg
• Flash Point: 82.3°C
• PSA: 26.30000
• Density: 1.078g/cm³
• LogP: 2.22040
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 162.068079557
• Heavy Atom Count: 12
• Complexity: 167

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)OC=CC1=CC=CC=C1
• Isomeric SMILES: CC(=O)O/C=C/C1=CC=CC=C1

Technology Process of Styryl acetate

There total 31 articles about Styryl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

cinnamic alcohol (30649-18-4,71195-15-8,4365-04-2) + acetic anhydride (108-24-7) → styryl acetate (10521-96-7) + acetic acid (64-19-7,77671-22-8)

Guidance literature:

With 3-((3-(trisilyloxy)propyl)propionamide)-1-methylimidazolium chloride ionic liquid supported on magnetic nanoparticle Fe₂O₃; at 20 ℃; for 5h;

DOI:10.1016/j.jmmm.2015.10.044

Reference yield: 58.0%

palladium diacetate (3375-31-3) + (Z,Z)-bis(2-phenylethenyl)telluride (105654-27-1) → styryl acetate (10521-96-7)

Guidance literature:

In acetonitrile; 2 equiv Pd(CH3COO)2, 25°C, 20 h; product ratio: E/Z=18/22 determined by GLC;

DOI:10.1016/0022-328X(92)83033-E

Reference yield: 56.0%

palladium diacetate (3375-31-3) + [(Z)-2-(phenyltellanyl)vinyl]benzene (82296-87-5) → styryl acetate (10521-96-7) + stilbene (588-59-0) + 1,4-diphenyl-1,3-butadiene (886-65-7,82598-07-0)

Guidance literature:

With triethylamine; In acetonitrile; 1 equiv Pd(CH3COO)2, 2 equiv Et3N, refluxing, 2 h; product ratio for 1,4-diphenylbuta-1,3-diene: E,E/E,Z/Z,Z=59/36/5 determined by GLC;

DOI:10.1016/0022-328X(92)83033-E

upstream raw materials:

sodium acetate

acetic anhydride

phenylacetaldehyde

(1R,6S,7S,8R)-7,8-dichlorobicyclo[4.2.0]octa-2,4-diene

Downstream raw materials:

formic acid

benzoic acid

1-acetoxy-1,2-diphenylethane

(E)-1,2-diphenyl-ethene

Refernces

• 1、 Khan, Faiz Ahmed,Choudhury, Sumit. "An efficient route to pentasubstituted phenols". . p. 672 - 676. Retrieved 2006.
• 2、 Sakakibara,Odaira. "". . p. 2049. Retrieved 1976.
• 3、 Brodzka, Anna,Koszelewski, Dominik,Ostaszewski, Ryszard,Trzepizur, Damian,Wilk, Monika. "Selective Palladium-Catalyzed α,β-Homodiarylation of Vinyl Esters in Aqueous Medium". supporting information. p. 6028 - 6036. Retrieved 2021/12/10.
• 4、 -. "Complex compound". Paragraph 0065; 0067. . Retrieved 2016/10/10.