4-(Chloromethyl)phenyltrichlorosilane

Base Information

• Chemical Name: 4-(Chloromethyl)phenyltrichlorosilane
• CAS No.: 13688-90-9
• Molecular Formula: C7H6Cl4Si
• Molecular Weight: 260.022
• Hs Code.: 2931900090
• European Community (EC) Number: 237-203-0
• DSSTox Substance ID: DTXSID3065584
• Nikkaji Number: J277.993E
• Wikidata: Q81992284
• Mol file: 13688-90-9.mol

Synonyms:13688-90-9;4-(Chloromethyl)phenyltrichlorosilane;Trichloro(4-(chloromethyl)phenyl)silane;trichloro-[4-(chloromethyl)phenyl]silane;(p-chloromethyl)phenyltrichlorosilane;p-(Chloromethyl)phenyltrichlorosilane;Benzene, 1-(chloromethyl)-4-(trichlorosilyl)-;Trichloro[4-(chloromethyl)phenyl]silane;Silane, trichloro(.alpha.-chloro-p-tolyl)-;Silane, trichloro[4-(chloromethyl)phenyl]-;EINECS 237-203-0;Silane, trichloro(4-(chloromethyl)phenyl)-;(p-Chloromethylphenyl)trichlorosilane;C7H6Cl4Si;C7-H6-Cl4-Si;SCHEMBL937352;4-Trichlorosilylbenzyl chloride;DTXSID3065584;4-(Trichlorosilyl)benzyl chloride;MFCD00045268;4-(chloromethyl) phenyltrichlorosilane;AKOS022180998;trichloro(4-chloromethylphenyl) silane;AS-66821;FT-0616730;J-006934

Chemical Property of 4-(Chloromethyl)phenyltrichlorosilane

Chemical Property:

• Vapor Pressure: 0.0114mmHg at 25°C
• Refractive Index: n20/D 1.549(lit.)
• Boiling Point: 270.4 °C at 760 mmHg
• Flash Point: 130.8 °C
• PSA: 0.00000
• Density: 1.38 g/cm³
• LogP: 3.28770
• Sensitive.: Moisture Sensitive
• Water Solubility.: Reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 259.896337
• Heavy Atom Count: 12
• Complexity: 137

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-(Chloromethyl)phenyltrichlorosilane, 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 14-34
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

Useful:

• Canonical SMILES: C1=CC(=CC=C1CCl)[Si](Cl)(Cl)Cl
• Uses: 4-(Chloromethyl)phenyltrichlorosilane is used as a pharmaceutical intermediate.

Technology Process of 4-(Chloromethyl)phenyltrichlorosilane

There total 2 articles about 4-(Chloromethyl)phenyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-tolyltrichlorosilane (701-35-9) → trichloro[4-(chloromethyl)phenyl]silane (13688-90-9)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); chlorine;

Reference yield:

→ trichloro[4-(chloromethyl)phenyl]silane (13688-90-9)

Guidance literature:

Aus p-Tolyl-trichlorsilan durch radikal. Chlorierung;

Reference yield: 90.0%

1,3,5,7,9,11,14-heptaisobutyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol (307531-92-6) + trichloro[4-(chloromethyl)phenyl]silane (13688-90-9) → C35H69ClO12Si8 (874748-98-8)

Guidance literature:

With trichlorosilane; In tetrahydrofuran-d8; at 0 ℃; for 0.25h;

DOI:10.1002/anie.201914889

upstream raw materials:

p-tolyltrichlorosilane

Downstream raw materials:

C₃₅H₆₉ClO₁₂Si₈

C₃₅H₆₉N₃O₁₂Si₈