p-Tolyltrichlorosilane

Base Information

• Chemical Name: p-Tolyltrichlorosilane
• CAS No.: 701-35-9
• Molecular Formula: C7H7Cl3Si
• Molecular Weight: 225.577
• Hs Code.: 29319000
• European Community (EC) Number: 211-854-0
• UNII: LX8V7HK9KM
• DSSTox Substance ID: DTXSID6061026
• Nikkaji Number: J193.063J
• Wikidata: Q72509336
• Mol file: 701-35-9.mol

Synonyms:p-Tolyltrichlorosilane;701-35-9;Trichloro-p-tolylsilane;Tolyltrichlorosilane;trichloro(p-tolyl)silane;Silane, trichloro(4-methylphenyl)-;trichloro-(4-methylphenyl)silane;p-Tolylsilyl trichloride;LX8V7HK9KM;Silane, trichloro-p-tolyl-;Benzene, 1-methyl-4-(trichlorosilyl)-;EINECS 211-854-0;Trichloro(4-methylphenyl)silane;4-Tolyltrichlorosilane;UNII-LX8V7HK9KM;4-methylphenyltrichlorosilane;p-Tolyltrichlorosilane, 95%;SCHEMBL301896;DTXSID6061026;Trichloro(4-methylphenyl)silane #;MFCD00045131;1-METHYL-4-(TRICHLOROSILYL)BENZENE;CS-0368291;FT-0605018;F83792

Chemical Property of p-Tolyltrichlorosilane

Chemical Property:

• Appearance/Colour: Colorless or yellowish transparent liquid
• Vapor Pressure: 0.251mmHg at 25°C
• Refractive Index: n20/D 1.5240(lit.)
• Boiling Point: 212.5 °C at 760 mmHg
• Flash Point: 94.8 °C
• PSA: 0.00000
• Density: 1.27 g/cm³
• LogP: 2.85730
• Sensitive.: Moisture Sensitive
• Water Solubility.: Reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 223.938260
• Heavy Atom Count: 11
• Complexity: 124

Purity/Quality:

99.9% ^*data from raw suppliers

p-Tolyltrichlorosilane 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 14-34
• Safety Statements: 23-26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)[Si](Cl)(Cl)Cl
• Uses: It can be used to produce 3-(p-Methylphenyl)cyclohexanon.

Technology Process of p-Tolyltrichlorosilane

There total 11 articles about p-Tolyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

para-methylphenylmagnesium bromide (4294-57-9) → p-tolyltrichlorosilane (701-35-9)

Guidance literature:

With tetrachlorosilane; In tetrahydrofuran; at 0 ℃; for 3h; Inert atmosphere;

DOI:10.1002/anie.202005341

Reference yield:

bis(p-tolyl)mercury (537-64-4) → p-tolyltrichlorosilane (701-35-9)

Guidance literature:

With tetrachlorosilane; at 300 - 320 ℃;

Reference yield:

toluene (108-88-3,15644-74-3,16713-13-6) → p-tolyltrichlorosilane (701-35-9) + m-tolyltrichlorosilane (13688-75-0)

Guidance literature:

With trichlorosilane; boron trichloride; at 200 ℃;

DOI:10.1021/ie50590a032

upstream raw materials:

bis(p-tolyl)mercury

toluene

para-methylphenylmagnesium bromide

trichlorosilane

Downstream raw materials:

triisopentyl-p-tolyl-silane

trichloro-(3-chloro-4-methyl-phenyl)-silane

trichloro[4-(chloromethyl)phenyl]silane

(3-bromo-4-methyl-phenyl)-trichloro-silane

Refernces

• 1、 Matsubayashi et al.. "". . p. 523. Retrieved 1973.