Bis (N, N-diethyldithiocarbamato)platinum(II)

Base Information

• Chemical Name: Bis (N, N-diethyldithiocarbamato)platinum(II)
• CAS No.: 15730-38-8
• Molecular Formula: C10H20 N2 Pt S4
• Molecular Weight: 491.626
• Hs Code.: 2930909090
• Mol file: 15730-38-8.mol

Synonyms:Platinum,bis(diethylcarbamodithioato-S,S')-, (SP-4-1)-; Platinum,bis(diethyldithiocarbamato)- (6CI,8CI);Bis(N,N-diethyldithiocarbamato)platinum; Bis(diethyldithiocarbamato)platinum;Bis(diethyldithiocarbamato)platinum(II); Bis(h2-diethyldithiocarbamato)platinum; NSC 148076;Platinum bis(diethyldithiocarbamate)

Chemical Property of Bis (N, N-diethyldithiocarbamato)platinum(II)

Chemical Property:

• PSA: 134.68000
• LogP: 3.08330

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bis (N, N-diethyldithiocarbamato)platinum(II)

There total 16 articles about Bis (N, N-diethyldithiocarbamato)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

dichloro(2,2'-bipyridine)platinum(II) (13965-31-6) + sodium N,N-diethyldithiocarbamate (148-18-5) → bis(N,N-diethyldithiocarbamate)platinum(II) (15730-38-8)

Guidance literature:

In not given; stoich. amts., stirring for 1 h (pptn.); collection (filtration), washing (water), drying (vac.);

Reference yield: 82.0%

potassium tetrachloroplatinate(II) (10025-99-7) + sodium N,N-diethyldithiocarbamate (148-18-5) → bis(N,N-diethyldithiocarbamate)platinum(II) (15730-38-8)

Guidance literature:

In water; at 20 ℃; for 1h;

DOI:10.1002/jccs.202000504

Reference yield:

cisplatin (15663-27-1) + diethyldithiocarbamate (392-74-5) → bis(N,N-diethyldithiocarbamate)platinum(II) (15730-38-8)

Guidance literature:

In water; a large excess of diethyl dithiocarbamate was added to a soln. of complex in water; ppt. was washed with water, centrifuged, dried in an oven at 60°Cfor 2 days;

DOI:10.1021/ic051904u

upstream raw materials:

cisplatin

diethyldithiocarbamate

carboplatinum

[Pt(ethylenediamine)((methylsulfanyl)acetato)]NO₃

Downstream raw materials:

{(η1-dpm)Pt(η2-S2CN(C2H5)2)(η1-S2CN(C2H5)2)}

NN-diethyldithiocarbamato(diphenylphosphinito)(methyl diphenylphosphinite)platinum(II)

NN-diethyldithiocarbamatobis(methyldiphenylphosphinite)platinum(II)tetraphenylborate

Refernces

• 1、 Clemente, Dore A.,Faraglia, Giuseppina,Sindellari, Livia,Trincia, Lucio. "Mixed Chloro-, NN-Dialkyldithiocarbamato-, and S-Alkyl NN-dialkyldithiocarbamate Complexes of Platinum(II). Crystal Structure of ". . p. 1823 - 1826. Retrieved 1987.
• 2、 Genre, Caroline,Levasseur-Theriault, Genevieve,Reber, Christian. "Emitting-state properties of square-planar dithiocarbamate complexes of palladium(II) and platinum(II) probed by pressure-dependent luminescence spectroscopy". . p. 1625 - 1635. Retrieved 2009.
• 3、 Adil, Syed Farooq,Al-Janabi, Ahmed S.,Al-Janabi, Emaad M. A.,Al-Jibori, Subhi A.,Faihan, Ahmed S.,Hatshan, Mohammad R.,Kadhum, Wesam R.. "Spectroscopic, antibacterial and anti-cancer studies of new platinum(II)-diethyldithiocarbamate mixed ligand complexes with phosphine or amine ligands". . . Retrieved 2021/12/27.